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Dimensional Analysis “Unit Factor Method”

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Presentation on theme: "Dimensional Analysis “Unit Factor Method”"— Presentation transcript:

1 Dimensional Analysis “Unit Factor Method”

2 How many seconds are in 2 years
How to convert 6 in to cm? Desired factor = cm, so you multiply it so that the units of inches cancel out Start off with the number with only 1 unit, and not two units. How many seconds are in 2 years Desired factor is seconds, you can multiply multiple factors but be sure that the factors cancel out!!!

3 Dim. Analysis in Chemistry
(6) How many atoms of hydrogen can be found in 45 g of ammonia, NH3? We will need three unit factors to do this calculation, derived from the following information: 1 mole of NH3 has a mass of 17 grams. 1 mole of NH3 contains 6.02 x 1023 molecules of NH3. 1 molecule of NH3 has 3 atoms of hydrogen in it.

4 Molarity Island When in doubt how to convert a measurement, convert it to moles first!

5 “The Conversion Triangle”
moles volume mass representative particles (22.4 L /mol)* (moles) (6.022 x 1023) (moles) (moles) * (6.022 x 1023) (liters) (22.4 L /mol) Representative Particles: element (contains) atoms ionic compound  (contains) ions molecular cmpd  (contains) molecules (moles) * (MW g/mol) (Grams) (MW g/mol) “The Conversion Triangle”

6 One Step Conversions The following three examples use “The Conversion Triangle” only once to solve the question.

7 Example Problem #1a How many moles are in 232.6 grams of C6H12O6?
Steps to solving this problem: 1. Find the molecular weight (MW) of the compound use a periodic table to find the molecular weights of the individual elements (MW are listed in “grams/mole”) C = 12 grams/mole H = 1 gram/mole O = 16 grams/mole 6 C* g/mol = 72 g/mol 12 H*1.007 g/mol = 12 g.mol 6 O*15.99 g/mol = 96 g/mol Total MW = g/mol C6H12O6 2. Convert grams to moles (using “The Conversion Triangle”) Example Problem #1a

8 Example Problem #1a Step 1 gave us:
MW of C6H12O6 = g/mol Step 2: Now to convert grams of C6H12O6 to moles (from “conversion triangle”) (grams C6H12O6 /MW C6H12O6) = moles C6H12O6 232.6 𝑔 𝐶6𝐻12𝑂6 1 ∗ 𝑚𝑜𝑙𝑒 𝑔 = 𝑚𝑜𝑙𝑒𝑠 With significant figures, the answer is 1.3 moles of C6H12O6 This is because the initial grams of C6H12O6 has only one significant figure Example Problem #1a

9 Example Problem #1b How many grams are in 3.2 moles of NaCl?
Steps to solving this problem: 1. Find the molecular weight (MW) of the compound use a periodic table to find the molecular weights of the individual elements (MW are listed in “grams/mole”) 1*Na = 1*23 g/mol 1*Cl = 1*35.5 g/mol Total Mw = 58.5 g/mol 2. Convert moles to grams (using “Conversion Triangle”) grams (mass) NaCl = moles NaCl * MW NaCl 3.2 𝑚𝑜𝑙𝑒𝑠 𝑁𝑎𝐶𝑙 1 ∗ 𝑔 𝑁𝑎𝐶𝑙 𝑚𝑜𝑙𝑒 =187.2 𝑔 𝑁𝑎𝐶𝑙 Answer only has 1 significant figure because initial value of moles has only 1 significant figure Example Problem #1b

10 1.65 𝑚𝑜𝑙𝑒𝑠 𝐶𝑎 1 * 6.022𝑥 10 23 𝑎𝑡𝑜𝑚𝑠 1 𝑚𝑜𝑙𝑒 =9.9336𝑥 10 23 𝑎𝑡𝑜𝑚𝑠 𝐶𝑎
How many representative particles are in 1.65 moles of Calcium (Ca)? Steps to solving this problem: 1. We already have moles of Ca, all we need to do is convert them to representative particles (or atoms) atoms Ca = moles Ca * 6.022x1023 atoms 1.65 𝑚𝑜𝑙𝑒𝑠 𝐶𝑎 1 * 𝑥 𝑎𝑡𝑜𝑚𝑠 1 𝑚𝑜𝑙𝑒 =9.9336𝑥 𝑎𝑡𝑜𝑚𝑠 𝐶𝑎 With significant figures: 9.93x1023 atoms Two significant figures in final answer are because of two significant figures in initial moles of Ca Example Problem #2

11 How many moles are in 1.32x1024 ions of compound “XYZ”?
Steps to solving this problem: We don’t need MW of compound XYZ to solve for how many moles are in it, all we need is Avagodro’s number and the Conversion Triangle moles XYZ = ions (representative particles) XYZ / 6.022x1023 ions 1.32𝑥 𝑖𝑜𝑛𝑠 𝑜𝑓 𝑋𝑌𝑍 1 ∗ 𝑚𝑜𝑙𝑒𝑠 6.022𝑥 𝑖𝑜𝑛𝑠 =2.192 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑋𝑌𝑍 With significant figures, the answer is 2.19 moles of XYZ Since the initial ions have only 2 significant figures, the answer must also Example Problem #2b

12 Example Problem #3a How many liters are in 4.32 moles of O2?
Equation from Conversion Triangle: liters O2 = moles of O2 * 22.4 L 4.32 𝑚𝑜𝑙𝑒𝑠 𝑂2 1 ∗ 𝐿 𝑚𝑜𝑙𝑒 = 𝐿 𝑂2 With significant Figures, the answer is 96.8 L of O2 Since the number of significant figures from 22.4 L is 1, the answer must also contain 1 significant figure Example Problem #3a

13 Example Problem #3b How many moles of N2 are in 150.2 L?
Equation from Conversion Triangle: Moles of N2 = liters of N2 / 22.4 L 150.2 𝐿 𝑂2 1 ∗ 𝑚𝑜𝑙𝑒𝑠 22.4 𝐿 =6.705 𝑚𝑜𝑙𝑒𝑠 𝑁2 With significant Figures, the answer is 6.7 moles of N2 Since the number of significant figures from 22.4 L and L are both 1, the answer must also contain 1 significant figure Example Problem #3b

14 Two Step Conversions The next two examples use “The Conversion Triangle” twice to solve the question.

15 Example Problem #1 How many liters (L) are in 28.3 g of Ne?
Steps to solve this problem: 1. Convert grams of Ne to moles of Ne get MW from periodic table then use Conversion Triangle to convert to grams  moles 2. Convert moles of Ne to L of Ne Solution: 1. moles of Ne = grams of Ne / MW of Ne MW of Ne = g/mol 28.3 𝑔 𝑁𝑒 1 ∗ 𝑚𝑜𝑙𝑒 𝑔 = 𝑚𝑜𝑙𝑒𝑠 𝑁𝑒 2. liters of Ne = moles of Ne * 22.4 L of Ne 𝑚𝑜𝑙𝑒𝑠 𝑁𝑒 1 ∗ 𝐿 𝑚𝑜𝑙𝑒𝑠 = 𝐿 𝑜𝑓 𝑁𝑒 Answer with significant figures: L of Ne Because initial grams of Ne and 22.4 L both have only one significant figure thus the answer should have only one significant figure Example Problem #1

16 Example Problem #2 How many grams are in 2.65x1020 ions of BaCl2?
Steps to solve this problem: 1. convert ions to moles 2. convert moles to grams get MW from periodic table then use Conversion Triangle to convert to moles  grams Solution: 1. moles of BaCl2 = ions of BaCl2 / 6.022x1020 ions 2.65𝑥 𝑖𝑜𝑛𝑠 1 ∗ 𝑚𝑜𝑙𝑒𝑠 6.022𝑥 𝑖𝑜𝑛𝑠 =4.4005𝑥 10 −4 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓BaCl2 2. grams of BaCl2 = moles of BaCl2 * MW of BaCl2 4.4005𝑥 10 −4 𝑚𝑜𝑙𝑒𝑠 BaCl2 1 ∗ 𝑔BaCl2 𝑚𝑜𝑙𝑒𝑠 = 𝑔 BaCl2 With significant figures, the answer is g BaCl2 Example Problem #2


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