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“Still Life With Apples”
Acids and Bases Paul Cezanne, “Still Life With Apples” 1890
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Definitions Bronsted-Lowry: Arrhenius: Acids donate protons (H+)
Bases accept protons (H+) Arrhenius: Acids produce hydronium in water (H3O+) Bases produce hydroxide in water (OH-)
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Properties of acids and bases
Property Acids Bases Product in water H3O+ OH- Protons? Donor Acceptor Taste Sour Bitter Feel Normal Wet Slippery Rxn with Metals Produce H2 No Reaction Rxn with Litmus Red Blue Rxn with Phenolphthalein Colorless Pink Electrical Conductivity Conducts Elec
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What is the conjugate base? What is the conjugate acid?
What is the acid? HNO3(aq) + NH3(aq) → NO3-(aq) + NH4+(aq) PO43- + CH3COOH → HPO42- + CH3COO- H2O + NH4+ → H3O+ + NH3 What is the base? What is the conjugate base? What is the conjugate acid?
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Strong vs. Weak Strong acids and bases ionize or dissociate completely (100%) Ex: HCl + H2O → H3O+ + Cl- NaOH → Na+ + OH- (all of the acid and base become products) Weak acids and bases ionize or dissociate only partially (<100%). They reach equilibrium. Ex: HNO2 + H2O ↔ H3O+ + NO2- NH3 + H2O ↔ NH OH- (only some of the acid and base become products)
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Strong Acids HCl: hydrochloric acid HBr: hydrobromic acid
HI: hydroiodic acid HNO3: nitric acid H2SO4: sulfuric acid HClO4: perchloric acid NOTE: HF and H3PO4 are not strong acids! Hydrogen Halides Oxyacids
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Strong bases LiOH Sr(OH)2 NaOH Ba(OH)2 KOH RbOH CsOH
Alkaline Earth Metals with OH- Alkali Metals with OH-
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How many protons? Look at these three acids:
HCl H2SO4 H3PO4 Which of the acids can give away the most protons (H+)? H3PO4! Since it can give away 3 protons, it is called a “triprotic acid.” Which acid do you think is monoprotic? HCl because it can only give away 1 proton. Which acid do you think is diprotic?
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How many protons? Acids that can give away more than one proton are called polyprotic. Acids that can give away only one proton are called monoprotic.
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