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Chemical Bonding 1
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2 GOALS 1. Compare & contrast ionic and covalent bonds in terms of electron position. 2. Predict formulas for stable binary ionic compounds based on balance of charges. 3. Use IUPAC nomenclature for transition between chemical names and chemical formulas of - binary ionic compounds - binary covalent compounds 4. Apply the Law of Conservation of Matter by balancing the following types of chemical equations: • Synthesis • Decomposition • Single Replacement • Double Replacement 34 16
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Why do Atoms Form Compounds?
3 Why do Atoms Form Compounds? Stability. What makes an atom stable? Full outer energy level. Eight. Chart page 576.
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Ionic Covalent A Chemical Bond holds atoms together in a compound.
4 A Chemical Bond holds atoms together in a compound. Two basic types: Ionic Covalent
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Ionic Bonding Transfer of electrons from one atom to another atom.
5 Ionic Bonding Transfer of electrons from one atom to another atom. Occurs between metals and nonmetals. Remember: Atoms need a full outer energy level to be stable. EIGHT!
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Occurs between metals and nonmetals.
6 Occurs between metals and nonmetals. Metals are electron donors. Non-metals are electron accepters. Called compounds.
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8 OPPOSITES ATTRACT!
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9 Ionic Bonding CLIP
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Covalent Bonding Occurs between nonmetals and nonmetals.
10 Covalent Bonding Occurs between nonmetals and nonmetals. The sharing of electrons between atoms. Called Molecules.
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12 Hydrogen and Fluorine Hydrogen and Chlorine
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13 Single, Double, Triple
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14 Clip
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When one atom has a greater positive charge
15 Unequal Sharing δ+ δ_ Polar When one atom has a greater positive charge
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NaPO4 CO2 HCl H2O NaF NaCl KCl MgCl2 CaCO3 NO2 N2 H2SO4 Cl2 NaF 16
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Writing Chemical Formulas Goals revisited
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17 The chemical formula for water is H2O. Carbon Dioxide is CO2.
Writing chemical formulas is a shorthand way of indicating what a substance is made of. These formulas also let you know how many atoms of each type are found in a molecule. The chemical formula for water is H2O. Carbon Dioxide is CO2. Why does oxygen combine in different ratios, in different compounds? The chemical formula for table salt is NaCl. Calcium Chloride is CaCl2. Why does chlorine combine in different ratios, in different compounds?
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The simplest compounds are ones with only two elements
18 The simplest compounds are ones with only two elements These are called binary KI, CO, H2O, NaCl
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Oxidation numbers +1 Tell you how many electrons an atom must gain, lose or share to become stable. -2 +2 +3 -3 -1 19
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All compounds are neutral That means the overall charge is ZERO!
20 Oxidation numbers We can predict the ratio of atoms in ionic compounds based on their oxidation numbers +1 -1 1 valence electron K Cl 7 valence electron All compounds are neutral Tells you how many electrons an atom must gain, lose or share to become stable. KCl That means the overall charge is ZERO!
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To make it ZERO, you need 1 Ca & 2 Br.
+1 -1 +2 -1 Na Br Ca Br To make it ZERO, you need 1 Ca & 2 Br. NaBr CaBr2 Subscripts show the number of atoms of that kind in the compound 21
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Some elements have more than one oxidation number (Chart p588)
+3 -2 +2 -2 Fe O Fe O Fe2O3 FeO We call these elements- Multivalent Elements 22
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Now You Try writing Binary Ionic formulas
K + Br Mg + Cl Ca + I K + O K + I Sr + Br Na + O Ga + Br Fe+2 + O Fe+3 + O Cu+2 + F Cr+3 + O Mg + O Al + P
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Groups of Covalently Bonded atoms that stay together.
24 Polyatomic Ions Cations: ammonium, NH4+ Anions: nitrate, NO3- sulfate, SO42- hydroxide, OH- phosphate, PO43- carbonate, CO32- chlorate, ClO3- permanganate, MnO4- chromate, CrO42- Groups of Covalently Bonded atoms that stay together.
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Try these……. Na + SO4 K + PO4 Mg + PO4 NH4 + NO3 Ca + CO3 H + SO4
25 Try these……. Na + SO4 Mg + PO4 Ca + CO3 Na + OH Mg + OH NH4 + OH K + PO4 NH4 + NO3 H + SO4 Ca + SO4 K + NO3 Na + PO4
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Naming Chemical Formulas
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Naming Binary Compounds and Molecules
26 Steps: If it is Binary- Decide if it is an ionic or covalent bond. Metal- nonmetal….. Ionic Nonmetal- nonmetal…. Covalent Example: NaCl
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If ionic ……. Examples: NaCl K2O AlCl3 BaF2 KI Li2O
Check to see if any elements are multivalent. If all single valent, write the name of the positive ion first. Write the root of the negative ion and add –ide.
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If ionic ……. FeO Fe2O3 CuO Cu2O PbCl4 PbI2 30 Examples:
Check to see if any elements are multivalent. If multivalent ions, determine the oxidation number of the element. Use Roman numerals in parentheses after the name of the element. Write the root of the negative ion and add –ide.
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31 If Covalent... Use Greek prefix to indicate how many atoms of each element are in the molecule Add -ide to the more electronegative element Greek Prefixes 1- mono- 2- di- 3- tri- 4- tetra- 5- penta- 6- hexa- 7- hepta- 8- octa- Example: NO Nitrogen Monoxide PCl3 Phosphorous trichloride
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If it contains a polyatomic ion...
32 If it contains a polyatomic ion... Write the name of the positive ion. Write the name of the polyatomic ion. Examples: NaCO3 KNO3 NaC2H3O2 Example: KOH Potassium Hydroxide CaCO3 Calcium Carbonate
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Name the following: CaSO4 KBr NH4OH HCl CaCO3 MgO Cu(ClO3) 2 CaCl
33 Name the following: CaSO4 NH4OH CaCO3 Cu(ClO3) 2 Cr2O 3 SrI 2 CCl4 KBr HCl MgO CaCl H2O NO2 CuSO4
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34 Writing & Balancing Chemical Equations Goals revisited
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35 Chemical Reactions A chemical reaction is a change in which one or more substances are converted into new substances. Rearrangement of bonds in compounds and molecules. Chemical Equations make it possible to see clearly what is happen during a chemical reaction
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Chemical equations are a shorthand way to show chemical reactions.
36 Chemical equations are a shorthand way to show chemical reactions. Reactants Products H2 + O2 H2O
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The mass of the products always equals the mass of the reactants
37 Conservation of Mass The mass of the products always equals the mass of the reactants
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2 Hydrogen atoms & one Oxygen atom
38 H2 + O2 H2O Does this meet the Conservation of Mass Law? 2 Hydrogen atoms 2 Oxygen atoms 2 Hydrogen atoms & one Oxygen atom Must Balance the Equation to show Conservation of Mass.
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39 Can add coefficients to Balance equations. 2 H2 + O2 2 H2O 4 2 2 2 4 2 1 Balanced!! Steps: 1. Count Atoms on both sides 2. If not Balanced, add coefficients to balance. 3. Recount atoms after adding each coefficient. 4. Keep adding coefficients until balanced.
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40 Types of Chemical Reactions
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Single Replacement (Single Displacement)
41 Synthesis Decomposition Single Replacement (Single Displacement) Double Replacement (Double Displacement)
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Synthesis “to make” A + B AB Cu + O CuO 2H2 + O H2O
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Decomposition “to breakdown” AB A + B 2H2O H O2 NaOH Na + OH
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When one element replaces another element in a compound
Single Replacement When one element replaces another element in a compound A + BC AC + B Cu+AgNO3 Cu(NO3)2+ 2Ag The more reactive metal will always replace the less reactive metal. (p749)
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Single Replacement Clip
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Double Replacement AB + CD AD + CB Ba(NO3)2+K2SO4 BaSO4 2KNO3 Clip
Positive Ion of One compound replaces the positive ion of another compound and a Precipitate is formed. AB + CD AD + CB Ba(NO3)2+K2SO BaSO4 2KNO3 Clip
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Chemical Reactions and Energy
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Chemical Reactions and Energy
51 Chemical Reactions and Energy All chemical reactions release or absorb energy. Heat, light, sound Chemical reactions are the making and breaking or bonds.
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1. Exergonic Chemical reactions that releases energy are called exergonic. Glow sticks If heat is released, it is called exothermic.
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2. Endergonic Chemical reactions that require energy are called endergonic. Ex: Cold Packs If heat is absorbed, it is called endothermic
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Catalysts and Inhibitors
Some reactions proceed slowly. They can be sped up by a catalysts. Catalysts are not used up in the reaction. EX: enzymes (biological catalysts) Some reactions proceed too fast. They can be slowed down by inhibitors. EX: Preservatives in food
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GOALS Revisited….. 1. Compare & contrast ionic and covalent bonds in terms of electron position. 2. Predict formulas for stable binary ionic compounds based on balance of charges. 3. Use IUPAC nomenclature for transition between chemical names and chemical formulas of • binary ionic compounds • binary covalent compounds 4. Apply the Law of Conservation of Matter by balancing the following types of chemical equations: • Synthesis • Decomposition • Single Replacement • Double Replacement
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