1. Effect of factors on PPD synthesis
초임계 암모니아를 이용한 고분자 합성 연구
Jin kyu Kang, Jae hwa kim, Jung woo Seo, Seok min Lee, Eun ho kim
Department of Chemical &Biomolecular Engineering, Sogang University, Seoul, Korea
Introduction
Introduction
Result & Discussion
Result & Discusstion
1. p-Phenylene diamine(PPD)
1. Effect of Temperature
H2N
NH2
Temperature : 30~200℃
Time : 1hour
NH3 gas : 20g
Catalyst : 0.2g
RPM : 1000
2. Application
2. Effect of Reaction Time
Temperature : 100℃
Time : 1~5hour
NH3 gas : 20g
Catalyst : 0.2g
RPM : 1000
2. PEDOT vs. PEDOT + buffer layer
3. Effect of Pressure
Process
Temperature : 150℃
Time : 1hour
NH3 gas : 5~20g
Catalyst : 0.2g
RPM : 1000
4. Effect of Catalyst
Temperature : 150℃
Time : 1hour
NH3 gas : 5~20g
Catalyst : 0~0.2g
RPM : 1000
Batch Reactor
Fabrication
Conclusion ` PG 1 2 3 4 5 6 7 8 9 10
Effect of factors on PPD synthesis
Reaction Temperature
Amount of NH3 gas
Reaction Time
CuI catalyst
Reactor (SUS316) : 100ml, 2. Heating jacket,
3. Valve, 4. Temperature sensor, 5. Pressure gauge,
6. Pressure sensor, 7. Temperature Controller,
8. Temperature gauge, 9. Pressure gauge,
10. Controller system
Best Conditions
Use
150℃
5 hour
20g