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The Atom & The Periodic Chart

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1 The Atom & The Periodic Chart
Basic Chemistry The Atom & The Periodic Chart

2 Atom Fundamental organizational unit of matter
Made up of smaller components Have a neutral charge

3 Atomic Structure Neutron: neutral charge Electron: - charge
Proton: + charge Neutron: neutral charge Electron: - charge

4 The Periodic Chart Chemical Symbol: abbreviated name of an element
1st letter always capital 2nd letter always lowercase Atomic Number: the number of protons in the nucleus of an atom # protons = # electrons because atoms are neutral the periodic chart is arranged by increasing atomic number Mass Number: the number of protons + the number of neutrons the mass of the atom 1 proton = 1 amu 1 neutron = 1amu the mass of the electron is so small it is ignored

5 1 Atomic Number Chemical Symbol Mass Number H 1.0079

6 Isotopes atoms with the same number of protons but a different # of neutrons number of neutrons changes the mass but not the charge this is the reason that the mass number is not a whole number

7 Isotope Examples Carbon -12 Carbon-14 6 protons and 6 neutrons 6+6=12
6+8= 14

8 Period: a row of elements on the periodic chart
= number of energy levels Group: a column of elements on the periodic chart have similar characteristics = number of valence (or outer) electrons

9 The Electrons Energy Levels: the route around the nucleus of an atom that an electron travels the bigger the orbit the more energy in the electron Orbitals: places within an energy level where electron tends to be found it is impossible to pinpoint exactly where an electron is located Valence Electrons: electrons in the outermost orbital determine properties of the element

10 Orbitals s p d f 1 2 x 8 6 3 18 10 4 32 14 5 7 Energy Level
Number of Electrons s p d f 1 2 x 8 6 3 18 10 4 32 14 5 7

11 s p d f

12 Write an electron configuration for Aluminum.
1s2 2p6 2s2 3s2 3p1

13 Al 1s2 2s2 2p6 3s2 3p1 The energy levels The orbital
The number of electrons The outermost energy level (this level houses the valence electrons) The valence electrons

14 A New Twist on Electron Configurations
The d and f orbitals lag behind

15 Uuo 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p6 Key Lagging 1 Level Behind Lagging 2 levels Behind

16 Another Twist

17 Stability Full Energy Level Full Sublevels Half Full Sublevels

18 Expect: [Ar] 4s2 3d9 Actually: [Ar] 4s1 3d10 Fill the lower level to increase stability Copper

19 chromium Expect: [Ar] 4s2 3d4
Actually: [Ar] 4s1 3d5 Half fill the lower level to increase stability chromium

20

21

22 Electronegativity: the higher the electronegativity the greater the ability to pull electron to itself

23 Atomic Size: the more energy levels the larger the atom the more electrons in the levels the greater their attraction to the nucleus (electrostatic attraction)


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