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Reaction Process
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A reaction mechanism is a step by step sequence of reactions that show an overall chemical change
The same reaction can occur by different pathways under different conditions. A species that appears in some steps but not in the overall equation is called an intermediate
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. Step 1 I2 ↔ 2I Step 2 2I + H2 ↔ 2HI I2 + H2 ↔ 2HI
A simple looking reaction like I2 + H2 2HI is more complex than it appears. This reaction has 2 possible reaction pathways. Step 1 I2 ↔ 2I Step 2 2I + H2 ↔ 2HI I2 + H2 ↔ 2HI
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A second pathway is as follows
Step 1 I2 ↔ 2I Step 2 I + H2 ↔ H2I Step 3 H2I + I ↔ 2HI I2 + H2 ↔ 2HI
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Homogenous reaction – reaction exists in a single phase
Heterogenous reaction – reaction is made up of materials in different phases
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Collision theory is an attempt to understand what happens to the individual molecules during a reaction. Molecules must have the proper energy and orientation for a reaction to occur. You need enough activation energy to create enough high energy collisions to get a reaction started. Once an exothermic reaction starts, it will sustain itself
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An activated complex is an intermediate material
An activated complex is an intermediate material. You need enough activation energy to create the activated complex.
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Reaction rates Reaction rate is the change in concentration of the reactants per unit of time Factors that influence reaction rates – presence of a catalyst, surface area, temperature, concentration A catalyst is a substance that speeds up a reaction without being consumed itself
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Experiments are conducted to find rate laws
The slowest step in any reaction is called the rate determining step A rate law is an equation the relates the reaction rate to the reactants
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