1. NEW products in Portfolio OF MOL GROUP Zuzana Kramárová Zoltán Hodik
PL ODOORS
Egerszalók,

2. agenda HIGH IMPACT PP TATREN IM 15 79 LDPE4 PROJECT ACTUAL STATUS
NEW LDPE GRADES FOR INJECTION MOULDING
NEWS IN HDPE PRODUCT PORTFOLIO
Overview of HDPE BLOW MOULDING GRADES

3. PP TATREN IM 15 79 CHARACTERISTIC APPLICATIONS HIGH ETHYLENE CONTENT
MFR
Tensile Strength at Yield
CHARACTERISTIC
HIGH ETHYLENE CONTENT
NON-PHTHALATE CATALYST
SYSTEM
NuCLEATING & ANTISTATIC
AGENT
Izod Impact resistance
Tensile Strain at Yield
Izod Impact resistance
Tensile Modulus
Flexural Modulus
APPLICATIONS
TOOL CASES
Medical waste containers
transposrt containers
Technical items

4. LDPE4 – Project actual status
ACTIVITY
PRODUCED GRADE
LYB CODING
APPLICATION
STATUS
Sustain Operation
FB 2-16
2420H
General purpose film
Bubble film
Foaming
ACCEPTED
Product Performance Tests
MB 36-36
FA 03-01
FB 08-50
FB 4-31
FD 4-33
2420T
1840D
2426F
2420K
3220K
Injection moulding
Masterbatches
Shrink film
Packaging film
Thin packaging film
PROVISIONAL ACCEPTANCE CERTIFICATE (PAC)
NOT SIGNED
TILL ODOR PROBLEM RESOLVING
Product performance tests finished in APRiL 2017

5. LDPE4 still in testing phase
LDPE4 – COMMErcial portfolio
Type
LYB Code
FB 03-02
2420D
FB 08-12
2420F
FB 08-50
2426F
FB 2-16
2420H
FB 2-51
2426H
FB 4-52
2426K
MB 7-30
2420M
MB 19-37
2420S
MB 36-36
2420T
FC 03-03
3020D
FC 08-13
3020F
FD 4-55
3426J
FA 03-01
1840D
MFR
0.3
0.8 2 4 7 19 36
3.5
Additive -
AB,SA(E)
Density
924
927
933
920
LDPE4 still in testing phase
Grades already produced.

6. LDPE4 – „TST“
RUNNING TESTS – to eliminate odor
ALL GRADES produced after start-UP 6/2017
EXCEPTION – FA 03-01, GA 03-04, GA 2-15
until THE FINal quality is reached
indication – bags, related documents
Processing OF „TST“ GRADES – AT THE SAME CONDITIONS AS „STANDARD“ GRADES
FA 03-01
GA 03-04
GA 2-15
FB 2-16 TST

7. Deadline to reach full food contact
FOOD CONTACT – Actual status
Sensory analysis compliance with Article 3, Regulation No. 1935/2004 *
GRADE
STATUS
Deadline to reach full food contact
FA 03-01
Comply -
GA 03-04
GA 2-15
FB TST
End of 9/2017
FB TST
FB 2-16 TST
GB 2-07 TST
*Measured according DIN at 40°C/48h in pre-cooked drinking water by multi-comparison paired test

8. Deadline to reach full food contact
FOOD CONTACT – Actual status
Sensory analysis compliance with Article 3, Regulation No. 1935/2004 *
GRADE
STATUS
Deadline to reach full food contact
FB 4-31 TST
Under testing ITC Zlín
End of 10/2017
FB 4-52 TST
FD 4-33 TST
FD 4-55 TST
MB TST
Samples preparation
MB TST
FB TST
FC TST
Planned production 9/17
End of 11/2017
FC TST
FB 2-51 TST
*Measured according DIN at 40°C/48h in pre-cooked drinking water by multi-comparison paired test

9. EE 243-51 MF 243-51 LDPE Injection moulding grades
Ldpe developments grades EE MF
Available for tests
Certificates expected:
FOOD
TOYS
PHARMA
Proposed Application Area:
General purpose flexible goods, technical items,
Compounding, masterbatches,
Extrusion coating (EE , EE partially)
Grade/ Parameter
Unit ED EE EE MF
Comonomer content
(%) 5
(Co-Po) -
(homo)
(co-po)
MFR (2.16 kg)
g/10 min
5.0
7.0
20.0
Density
kg/m3
918
922
Modificator
Propene
Propion-aldehyde
Vicat softening temperature °C NA 82 80
Next step: ED to aim full applicability for extrusion coating
(for high speed and very thin coatings as well)

10. 1100J 1108J Injection moulding grades Certificates: FOOD TOYS
hdpe developments grades
1100J
1108J
Proposed Application Area:
Certificates:
FOOD
TOYS
PHARMA: 1100J
Daily necessaries,
Boxes, crates, trays
Toys, caps, cartridges
Grade/ Parameter
Unit
1100J
1108J
Additive content
Basic
Basic + UV
MFR (2.16 kg)
g/10 min
8.0
Density
kg/m3
961
ESCR (100% Igepal, F50) h 9
IZOD (notched, 23 °C)
kJ/m2 5

11. CO2 Certificates: 1100J 2100J 1108J 2108J FOOD TOYS PHARMA: 2100J
Injection moulding grades
hdpe developments grades
1100J
2100J
1108J
2108J
Certificates:
FOOD
TOYS
PHARMA: 2100J
Grade/ Parameter
Unit
2100J
2108J
Additive content
Basic
Basic + UV
MFR (2.16 kg)
g/10 min
4.0
Density
kg/m3
953
ESCR (100% Igepal, F50) h 12
IZOD (notched, 23 °C)
kJ/m2 7
CO2
Aim:
Achieve 10 kJ/m2 IZOD Impact Strength
Next step:
Narrower MWD, lower MFR and density
Proposed Application Area:
Industrial scale products, bins
Boxes, crates, trays, pallets
Basins, laundry baskets, bottle closure for non-carbonated drinks 11

12. (carbonated soft drinks)
Injection moulding grades
hdpe developments grades
1100J
2100J
3100J
1108J
2108J
3110J
Caps & closures for CSD
(carbonated soft drinks)
FOOD
TOYS
PHARMA: 3100J
Certificates:
Excellent organoleptic properties
Grade/ Parameter
Unit
3100J
3110J
Additive content
Basic
Basic + SA
MFR (2.16 kg)
g/10 min
2.2
Density
kg/m3
952
ESCR (10% Igepal, F50) h
>20
IZOD (notched, 23 °C)
kJ/m2 11
available for tests
Easy
opening & handling 12

13. 1900J 2900J 2100J 1900J 6000B 2108J 2900J Industrial products 1100J
17/06/2018
Further injection moulding grades
HDPE for injection moulding
1900J
2900J
Characteristics:
Not constant composition
Tendency in parameters
Applications:
Industrial products
Houseware products
2100J
2108J
1900J
2900J
1100J
1108J
6000B
Grade/ Parameter
Unit
1900J
2900J
Additive content
Not constant (AO, SA, UV)
MFR (2.16 kg)
g/10 min
3.0 – 7.0
Density
kg/m3
Grades are not in production schedule.

14. HDPE grades for blow mouldinG, Corrugated pipes
and (thermoformed) sheets (MFR2,16 < 0,2)
Products are finalized
and continuously available
MFR2,16
MFR21,6
Density
Flexural mod.
Impact strength
ESCR
OIT
Notes
ISO 1133
ISO 1183
ISO 178
ISO 180/A ***
ASTM D 1693
EN 728
Grade
modality
g/10 min
kg/m3
Mpa
kJ/m2 h
min BB
unimodal
0,65 50
962
1900 14
18 ** 8
Small bottles up to 1 liter
For non-agressive liquids BA
0,35 28
955
1600 15
45 ** 10
Bottles, cans up to 30 liters
6000B
bimodal
0,3 30
958
1700 9
200 *
Bottles, cans up to 5 liters
For agressive liquids
6010B **** 90
6300B
954
1550
500 * 34
Bottles, cans up to 10 liters
6301B ***** BS
0,2 22
950
1400
180 ** 7 BS
0,1
952
1450 29
540 **
Cans, drums up to 220 liters
7300B 11 18
1375 * 53
Cans, balloons up to 60 liters
8200B
0,025 6
1300 31
> 1200 * 85
Cans, containers up to 1000 liters
* in 10% detergent
** in 100% detergent
*** Notched Izod
**** Lon-term natural colour stability
***** Increased heat stabilit for in-house filling technology
Certificates:
FOOD
PHARMA
Toys

15. Thank you for your attention