1. Lauren, Allison and Caelin
Amines and Amides
Lauren, Allison and Caelin

2. Amines Most common organic bases Ammonia derivatives
1+ hydrogen atoms have been replaced by a carbon/substituent
C dawg

3. There are primary, secondary and tertiary amines
Structure
There are primary, secondary and tertiary amines
C talk l hold and look pretty

4. Properties Base because of pair of unshared electrons
Substituent can be aromatic
Polar
High melting and boiling points
Smaller-Ammonia smell
Larger-Fishy or decaying smell

5. Naming Parent chain is longest carbon chain attached to the N
Remove –e from corresponding alkane name and use the suffix amine
Number the carbon in the parent chain to which the N is attached
Other carbon chains on the nitrogen are substituents named with N-
Sometimes it is necessary to name the amine group as a branch, use the prefix amino- in this case

6. methan-1-amine
N-methylbutan-1-amine
N-ethyl-N-propylbutan-1-amine

7. N,N-dimethylmethan-1-amine

8. How many ways can you name the most basic amine?

9. Methylamine
Methanamine
Aminomethane

10. Reactions involving amines
Alkyl halide+Ammonia=1 Amine
Alkyl halide+1 Amine=2 Amine
Alkyl halide+2 Amine=3 Amine

11. Amides
An amide is an organic compound that contains a carbonyl group bonded to a nitrogen atom
Similar to esters but with a nitrgen bonded not an oxygen

12. Naming Parent chain is the one with C-O Use the suffix –amide
-1st part comes from the amine
-2nd part comes from the carboxylic acid
*If other attachments then N- is used

13. ethanamide
N-methylbutanamide

14. N,N-diethyl-2-ethylpentanamide

16. Properties Amides are weak bases
Low molecular weight amides are soluble in water
They have the ability to hydrogen bond
High melting and boiling points
Methanamide is liquid at room temperature, all others are solid

17. + = Reactions of Amides N-methylbutylamide
Preparing amides from amines and carboxylic acids +
Condensation Reaction =
N-methylbutylamide

18. Caffeine
Serotonin
Amide
Amine
Morphine
Cadavorine
Amine
Amine

19. https://amazingamidesandamines.wikispaces.com/Videos

20. Resources
Atkins, P; Jones, L (1989) Chemistry Molecules, Matter, and Change Third Edition. W.H. Freeman and Company: New York
Dpcdsb.org editors Amines and Amides pdf. Retrieved September 22, 2016 from
Eastern Kentucky University Chapter 15 Amines and Amides. Retrieved September 23, 2016 from
Goldsmith, David J; Mandell, L; Menger, Fredric M (1972) Organic Chemistry A Concise Approach. W.A. Benjamin, Inc.
Ktgss.edu.hk editors Academic Chemistry Amide. Retrieved September 30, 2016 from
Unknown Author(s) Amines and Amide. Retrieved September 24, 2016 from
Unknown Author(s) Naming Amines and Amides Rules. Retrieved September 23, 2016 from

21. Thanks!
Any questions?

22. Time for our game!