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Chapter 15 Aqueous Solutions – something is dissolved in water
Solvent – what the stuff is dissolved in (is always the larger amount)
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A Solute dissolves in water (or other “solvent”)
*the solute is dissolved in the solvent* is always the lesser amount
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Effect of Temperature Increasing T will cause more solid to dissolve in the solvent Increasing T will cause less gas to dissolve – (think soda pop)
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Effect of surface area Increasing surface area will cause more solid to dissolve more quickly: When more of the solid is in contact with the solvent, it can dissolve better We can increase the surface area by grinding chunks into a powder
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Using a volumetric flask to make a solution
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pure water, sugar solution
Electrolytes Strong - conduct current efficiently NaCl, HNO3 Weak - conduct only a small current vinegar, tap water Non - no current flows pure water, sugar solution
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Concentrated solution: has a lot of solute in it
Dilute solution: has very little solute in it Saturated solution: no more solute can be dissolved
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Acids Strong acids -dissociate completely to produce H+ in solution
hydrochloric and sulfuric acid Weak acids - dissociate to a slight extent to give H+ in solution acetic and phosphoric acid
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HCl is strong so it’s completely ionized split apart!
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Acetic acid (HC2H3O2) is weak so it mostly stays together NOT split!
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Bases Strong bases - react completely with water to give OH ions.
sodium hydroxide Weak bases - react only slightly with water to give OH ions. ammonia
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Mass Percent Mass percent = mass of solute X 100 mass of solution
Mass of solution = solute g + solvent g
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Question A solution is prepared by mixing 5.00 g of ethanol with g of water. Calculate the mass percent of ethanol.
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Question Cow’s milk contains 4.5% by mass of lactose, C12H22O11. Calculate the mass of lactose present in 175 g of milk.
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Molarity Molarity (M) = moles of solute
per volume of solution in liters: 3M can be written as 3 mol 1 L
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Question Calculate the molarity of a solution prepared by dissolving 1.56 g of HCl in enough water to make 26.8 mL of solution.
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QUESTION
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ANSWER
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Question How many grams of NaCl would be required to make 500 mL of a 1.5 M solution.
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Question What is the concentration of each ion in a solution of 0.25M K3PO4 ?
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question How many moles are in 10.2 mL of M AlCl3?
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question How many grams are in 1.75 mL of 1.25M CuCl2?
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Dilution Water is added to lower the concentration
Only one compound is involved M1(V1) = M2 (V2)
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QUESTION
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ANSWER
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400 mL of water is added to 150 mL of 0. 45 M NaOH
400 mL of water is added to 150 mL of 0.45 M NaOH. What is the molarity of the resulting solution?
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Calculate the volume of 0. 1M NaOH needed to react with 150 mL of 0
Calculate the volume of 0.1M NaOH needed to react with 150 mL of 0.35M H2SO4. Write the reaction Pick the substance that you know both M and mL for and start with the mL
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Use reaction to get molemole
H2SO4 + 2NaOH Na2SO4 + H2O 4. Use the other molarity to get the volume
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question What mass of NaCl must be added to 1.5 L of 0.100M AgNO3 solution to precipitate all of the silver as AgCl?
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question Calculate the molarity of NaOH if 27.6 mL reacts with 65.4 mL of a 0.15M solution of H2SO4.
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