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Acid Base Reactions & Theories
Chapter 20 part III
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Acid Base Reactions Acid Anhydrides & water form Acid
SO3 + H2O H2SO4 Acids & Metals form Salt and Hydrogen Gas 2HCl + Mg H2 (g) + MgCl2 Acid & Base Form Salt & Water HNO3 + KOH H2O + KNO3 Acid and Carbonates form Carbon dioxide, salt & water 2HCl + MgCO3 H2O + MgCl2 + CO2
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Neutralization reactions
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Arrhenius Theory Arrhenius proposed (1883) that ionic compounds dissociate and can become free ions acting as separate entities in solution.
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Arrhenius Theory ACID: Produces H+1 in Water BASE: Produces OH-1 in Water HCl(aq) H+1 + Cl-1 HNO3(aq) H+1 + NO3-1 NaOH(aq) Na+1 + OH-1 NH3(aq) NH4+1 + OH-1
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Bronsted/Lowry Theory
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Bronsted & Lowry proposed a new acid-base theory in 1923.
ACID: PROTON DONOR BASE: PROTON ACCEPTOR
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Also: Since protons are always transferred in the Arrenhius theory, all Arrhenius acid/base reactions are also Bronsted-Lowry acid/base reactions. Bronsted-Lowry theory expands Arrenhius theory to include any proton transfer (water not required).
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Lewis Theory In 1938 Gilbert Lewis proposed a more general acid base theory.
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Lewis Acids ACID: Accepts pair of electrons for sharing BASE: Donates pair of electrons for sharing
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