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Warm-Up A 55ml sample of a 0.102M potassium sulfate solution is mixed with 35ml of a 0.114M lead(II) acetate solution and this precipitation reaction occurs K2SO4(aq) +Pb(C2H3O2)2(aq) KC2H3O2(aq)+PbSO4(s) The solid PbSO4 found to have a mass of 1.01g .Determine the limiting reactant, the theoretical yield and percent yield?
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Strong acids and weak Acids
Strong acids dissociate completely in water Example: HCl Weak Acids: They do not completely dissociate in water Example : acetic acid Strong acids are strong electrolytes and weak acids are weak electrolytes
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Solubility Rules for Ionic compounds in Water
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Predict the solubility
NiS Mg3(PO4)2 Li2CO3 NH4Cl
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Precipitation Reactions
Hard water – contains dissolved ions such as Ca2+ and Mg2+ which diminishes the effectiveness of soap Most laundry detergents contains substances such as sodium carbonate to remove these ions Na2CO3 (aq) --> 2Na+(aq)+ CO3 2- (aq)
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Hardness of water The carbonate ions react with Ca2+ and Mg2+ ions to form precipitate which prevent their reaction with soap Ca2+(aq) + CO32- → CaCO3(s) + 2Na+(aq) Mg2+(aq) + CO32- → MgCO3(s) + 2Na+(aq) These reactions are called precipitation reactions
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Precipitation reactions
Pb(NO3)2(aq)+ 2KI(aq) = 2KNO3(aq) + PbI2(s) (Soluble) (soluble) (soluble) (insoluble) KI+NaCl No reaction happens Only insoluble compounds form precipitate
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How to represent Aqueous Reactions
Aqueous reaction can be represented by molecular, net ionic and complete ionic equations Molecular Equation – represents all the molecules Pb(NO3)2(aq)+ 2KI(aq) = 2KNO3(aq) + PbI2(s)
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Complete ionic Equation
Equations list all of the ions present as either reactants or products present in a reaction are complete ionic equation Pb2+(aq) +2NO3-(aq) +2K+(aq)+2I-(aq) PbI2(s)+2K+(aq)+ 2NO3-(aq) Strong electrolytes are always represented as their component ions in ionic equation
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Spectator Ions Some of the ions in the equation remains unchanged on both sides of the equation. They are called spectator ions They do not participate in the reaction
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Net Ionic equation Equation that shows only the species that actually change during the reaction are called net ionic equation
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Write the molecular equation, complete ionic equation and net ionic equation for the following reaction HCl(aq) + KOH(aq) = KCl(aq) + H2O(l)
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