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Reactions in Aqueous Solutions
Unit 4: Reactions in Aqueous Solutions Day 2: Letter to District and Precipitate Reactions
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Warm Up ANSWER: The following questions: TIME: 6 MINUTES
How has our classroom situation affected your level of engagement in AP chemistry? How does it make you feel about having less hands-on activities in chemistry? What kinds of solutions do you think we can do to make our classroom situation better? TIME: 6 MINUTES WHEN DONE: Show me for a stamp
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TURN AND TALK TO A TABLE PARTNER ABOUT WHAT YOU WROTE
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Agenda Letter to District Progress Reports and Conference Reflection
Double Displacement/Metathesis Reactions Ways to Represent Metathesis Rxn Guided Inquiry: Net Ionic Equations
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Letter to District THINGS TO INCLUDE: Your name, class period, date
USE: Your warm up and our discussion to help guide your letter THINGS TO INCLUDE: Your name, class period, date Sincerely, Your Name__ THINGS TO MENTION: Reasons you are taking chemistry (hands on science, future goals Labs shortened or eliminated or replaced with videos How you feel not being in your science classroom How other classes are affected TIME: 13 MINUTES WHEN DONE: Turn into class box or bring it to conferences and begin conference reflection sheet
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Conference Reflection
VIEW: Your progress and attendance report COMPLETE: Student-Led Conference Reflection For 4: Answer every question and BE SPECIFIC AND DETAILED! TIME: 13 MINUTES WHEN DONE: Staple in this order and turn into class box Reflection Progress Report Attendance Report This CONFERENCE REFLECTION IS for a PRACTICE grade (even if you are NOT coming to conferences)
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Discussion What would make this class better?
What would you like to see me do differently to help you be more successful?
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Discussion CONTINUE CATCHING UP ON MISSING WORK
Get Notes Watch Video on WEBSITE about Net Ionic Equations MOVE FORWARD WITH TODAY’S PLAN
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Lecture Notes Topics: What’s Important?
Definitions: Electrolyte (strong vs. weak) Non-electrolyte Dissociate Precipitate Solubility (and guideline table) Metathesis Reactions Types of Equations: Molecular Complete ionic Net ionic Neutralization Strong Acids vs. Strong Bases
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Lecture Notes Topics: What’s Important?
Processes How to identify strong vs. weak electrolytes How to predict precipitates How to predict metathesis reactions How to write a molecular equation How to write a net ionic equation How to write a neutralization reaction
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What do I need to memorize and what do I need to just practice with?
Memorize Practice Definitions Table 4.1, p Solubility Guidelines Table 4.2, p Activity Series, p. 144 Table 4.3, p Steps for Molecular Eq Molarity equation Steps for Net Ionic Eq Dilution equation Steps for Neutralization
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Review Definitions Solutions are defined as homogeneous mixtures of two or more pure substances. Solutions are made of solvents and solutes. Let’s say you make a chocolate milk “SOLUTION” by mixing Nestle Quik powder with Milk. WHICH IS THE SOLUTE? NESTLE QUIK OR MILK? Solute = nestle quik
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Aqueous Solutions Ionic Compounds: Dissociate completely (separate into ions) Molecular Compounds: Sometimes dissolve, but DO NOT dissociate (because molecular compounds do not “transfer” electrons, they “share” electrons)
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Electrolytes and Nonelectrolytes
An electrolyte is a substance that dissociates into ions when dissolved in water. A nonelectrolyte may dissolve in water, but it does not dissociate into ions when it does so. Classify the following compounds: NaCl, CH3OH, HCl, C3H8O3, NH3PO4, LiOH, HNO3, NH3, C12O22H11 STRONG WEAK NON- ELECTROLYTE NaCl NH3PO4 CH3OH HCl NH C3H8O3 LiOH C12O22H11 HNO3
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METATHESIS REACTIONS Molecular Equations Complete Ionic Equations
Net Ionic Equations Neutralization Reactions Gas Forming Reactions
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Metathesis (Exchange) Reactions
Metathesis comes from a Greek word that means “to transpose.” It appears as though the ions in the reactant compounds exchange, or transpose, ions, as seen in the equation below. AgNO3(aq) + KCl(aq) AgCl(s) + KNO3(aq)
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Completing and Balancing Metathesis Equations
Steps to follow Use the chemical formulas of the reactants to determine which ions are present. Write formulas for the products: cation from one reactant, anion from the other. Use charges to write proper subscripts. Check your solubility rules. If either product is insoluble, a precipitate forms. Balance the equation.
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Which of these are soluble?
(NH4)2S, CaCO3, NaOH, Ag2SO4, Pb(CH3COOH)2
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Predict the identity of the precipitate…
When MgCl2 and CaS are mixed. Write the balanced equation. MgCl2 + CaS = MgS + CaCl2
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Predict the identity of the precipitate…
When solutions of Fe2(SO4)3 and LiOH are mixed. Write the balanced equation. Fe2(SO4)3 + LiOH = Fe(OH)3 + Li2SO4
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Yes or No? Will a precipitate form when Ba(NO3)2 and KOH are mixed?
Ba(NO3)2 + KOH = Ba(OH)2 + KNO3 (No, both products are soluble)
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Ways to Write Metathesis Reactions
Molecular Net Ionic Complete Ionic
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AgNO3(aq) + KCl(aq) AgCl(s) + KNO3(aq)
Molecular Equation The molecular equation lists the reactants and products without indicating the ionic nature of the compounds. AgNO3(aq) + KCl(aq) AgCl(s) + KNO3(aq)
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Complete Ionic Equation
In the complete ionic equation all strong electrolytes (strong acids, strong bases, and soluble ionic salts) are dissociated into their ions. This more accurately reflects the species that are found in the reaction mixture. Ag+(aq) + NO3−(aq) + K+(aq) + Cl−(aq) AgCl(s) + K+(aq) + NO3−(aq)
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Net Ionic Equation To form the net ionic equation, cross out anything that does not change from the left side of the equation to the right. The ions crossed out are called spectator ions, K+ and NO3−, in this example. The remaining ions are the reactants that form the product—an insoluble salt in a precipitation reaction, as in this example. Ag+(aq) + NO3−(aq) + K+(aq) + Cl−(aq) AgCl(s) + K+(aq) + NO3−(aq)
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Writing Net Ionic Equations
Write a balanced molecular equation. Dissociate all strong electrolytes. Cross out anything that remains unchanged from the left side to the right side of the equation. Write the net ionic equation with the species that remain.
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Writing Net Ionic Equations
Write the net ionic equation for the reaction that occurs when aqueous solutions of silver nitrate and potassium phosphate are mixed.
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