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Characteristics of the humic substances in sugarcane cultivated soils of Minami daito and Kita daito islands in Japan. INTRODUCTION ●Sugarcane yields in Minami daito and Kita daito islands in Japan showed a declining tendency in recent years. 10 Minami daito island Kita daito island 8 ●The cause of the decline in sugarcane yields may be low content of humic substances. 6 Yields(t/10a) 4 ●A study was conducted to examine the characteristics of the humic substances, which are being considered of having close relationship with the properties of sugarcane cultivated soils. 2 1995 1997 1999 2001 2003 (Year) Yields of sugarcane in Minami and Kita daito islands, Japan. Sampling sites Methods ●Soil chemical and mineralogical properties were determined. 131°20′N K-6 K-7 K-5 ●Humic substances were extracted and quantified according to the method described by Kumada (1977). K-4 K-8 K-3 K-1 <Kita daito island> K-2 K-9 <Kumada method> M-11 Soil sample M-14 M-8 0.1M NaOH+ 0.1M Na4P2O7 M-12 M-10 M-9 <Minami daito island> Precipitation (insoluble fraction ; humin) M-4 M-7 Supernatant 25°50′E M-6 0.1M H2SO4 M-1 M-13 km M-3 M-5 M-2 Humic acid (precipitation) Fulvic acid (Supernatant) ●Sugarcane cultivated soils in two islands is classified into calcareous soil. *Humic acid, fulvic acid and humin were determined by back titration using the potassium permanganate solution. ●Sugarcane cultivated soils were collected from 9 fields in Kita daito island and 14 fields in Minami daito island, respectively. ●Collected surface soils were utilized characterize the humic substances. *The degree of humification was determined by calculating ΔlogK(logK400nm-logK600nm) and RF({K600nm×1,000} / {0.1N KMnO4 consumption(mL) / 30mL of humic acid solution)
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●Kazutoshi Kinjo1, Koichi Yoshida2, Yoshihiro Tokashiki1, Makoto Kitou1, Yasushi Gima3, Shigeru Kameya3 and Naoko Miyamaru3 1). Faculty of Agriculture, University of the Ryukyus,Okinawa, Japan, 2). Okinawa Agricultural Technology & Dvelopment Office, 3). Okinawa Prefectural Agricultural Research Center Results & Discussions ⇒Soil pH and EC of the soils from both islands were in the range of about and S/cm, respectively. The results of XRD indicated that kaolinite and illite were the most predominant mineral in all soils. Soil texture was almost heavy clay in all soils. <Humification of humic acids of sugarcane surface soils> ⇒The degree of humification of humic acids in sugaracane soils showed a low degree(Rp type). Rp B A P 160 ⇒The percentage of humin, fulvic acids and humic acids contents in Total humic substances were 42%, 37% and 20%, respectively. Content of humic and fulvic acids and humin (g/kg) 3.0 120 2.0 80 ⇒The low degree of humification is classified into degradation-resistant categories of which the materials are lignin, tannin and melanoiding. RF 1.0 40 0.0 Humic acid (HA) Fulvic acid (FA) 1.1 0.9 0.7 0.5 Humin ⊿log K Significant correlation coeficients (Kita daito and Minami daito islands,n=23, **1%, *5%) Coarse sand Fine sand pH(KCl) Humin T-HS Na Ca Mg Silt Clay pH(H2O) 0.994** 0.471* 0.837** 0.693** 0.421* -0.410* pH(KCl) 0.471* 0.854** 0.651** 0.424* -0.414* EC 0.590** HA 0.524** FA 0.419* -0.601** -0.483* Humin 0.619** 0.626** ⊿logK -0.406* Na 0.429* K -0.575** -0.568** Ca 0.458* 0.514* -0.445* Fine sand 0.761** -0.515* ●Soil organic matter(humin) accumulation in the sugarcane soils has been enhanced by the presence of exchangeable calcium. ●It was suggested that liming materials, which are having high concentrations of calcium, can be effectively utilized to enhance the soil organic matter(humin) accumulation to improve the soil properties.
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