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Unsaturated Hydrocarbons
Organic Chemistry
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Unsaturated Hydrocarbons
Any hydrocarbon that has a __________________________________ bond (s) Refers to the idea that the carbons have __________________________________________attached to them as compared to alkanes A place (s) where additional hydrogens would be attached has a double or triple bond (s) instead Examples include: __________________________________________
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Alkenes 3 Sometimes, carbon forms sp2 hybrids.
Made by an __________________________. They are ______________________________. The three sp2 hybrid orbitals arrange themselves as far apart as possible - which is at 120° to each other in a plane. The remaining p orbital is at right angles to them.
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Organic Chemistry
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These orbitals form a double bond.
Organic Chemistry These orbitals form a double bond.
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Organic Chemistry Ethene
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Figure 11.10 The s and p bonds in ethylene (C2H4) overlap in one position - s p overlap - electron density
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Organic Chemistry Hydrocarbons that contain only carbon and hydrogen and have at least one carbon carbon _________________bond are called _______________.
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2 Ethene 3 Propene 4 1-Butene _______________
Organic Chemistry Alkenes end in ene and the prefix tells you how many carbon atoms are present.’ 2 Ethene 3 Propene 4 1-Butene _______________
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The number tells you where the _________________ is located.
Organic Chemistry The number tells you where the _________________ is located. ______________ CH2=CH-CH2-CH3 ______________ CH3-CH=CH-CH3
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Start numbering at the end closest to the double bond
Organic Chemistry Name this compound. Start numbering at the end closest to the double bond
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__________________________
Organic Chemistry 1 2 3 5 4 __________________________
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Figure 11.12 Restricted rotation of p-bonded molecules CIS TRANS
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Alkenes Important in manufacturing and in human and plant functioning
Hormones Ripening fruit Ethene used to make polymers
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Alkynes Sometimes the carbon atoms use the 2s electron and one of the 2p electrons, but leave the other 2p electrons unchanged. The new hybrid orbitals formed are called sp1 hybrids because they are made by an s orbital and a single p orbital. This forms a ______________________
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Organic Chemistry
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Organic Chemistry Ethyne CHCH or C2H2
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Figure 11.11 The s and p bonds in acetylene (C2H2) overlap in one position - s p overlap -
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The number tells you where the triple bond is located.
Organic Chemistry Hydrocarbons that contain only carbon and hydrogen and have at least one carbon carbon ___________ bond are called _______________. Alkynes end in yne and the prefix tells you how many carbon atoms are present.’ The number tells you where the triple bond is located.
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Organic Chemistry Name this compound
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Organic Chemistry 6 4 3 2 1 5
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___________________________
Organic Chemistry 6 4 3 2 1 5 ___________________________
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Alkynes Not found in nature often Acetylene used in welding torches +
Ch---CH +
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Benzene is the simplest aromatic compound
Aromatic Compounds Unsaturated cyclic hydrocarbons are known as _________________________________________ Benzene is the simplest aromatic compound
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Aromatic Compounds Benzene is An aromatic compound.
A ring of 6 C atoms and 6 H atoms. Alternating _________________________bonds Aromatic compounds often have _________
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Aromatic Compounds in Nature and Medicine
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