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CHEMISTRY I. Introduction A. Why study chemistry? B. Definitions
1. Chemistry (study of matter) 2. Matter (mass and space)
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3. Element (natural stable particles of matter)
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4. Molecule (combining atoms) 5. Compound (atoms in a fixed ratio)
Figure 2.1
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Figure 3.4B
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II. Atomic Chemistry A. Particles / Structure Figure 2.3A
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B. Atomic Number & Mass Number
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C. Isotopes & Radioisotopes
Figure 2.4B Table 2.3 1. Isotopes = varied number of neutrons but stable 2. Radioisotopes = nucleus decay giving off alpha and beta particles, plus gamma rays. 3. Decay = half life How and why would this activity be so bad for cells?
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D. Electrons 1. Shells electron organization Figure 2.5
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Sub shell Electron Configuration
Atom No. Electrons Sub shell Electron Configuration Ion H 1 1s1 H- 1 + 1 = 2 1s2 He 2 Li 3 1s2 2s1 Li+ 3 - 1 = 2 Be 4 1s2 2s2 Be2+ 4 - 2 = 2 B 5 1s2 2s2 2p1 B3+ 5 - 3 = 2 C 6 1s2 2s2 2p2 C4+ 6 - 4 = 2 N 7 1s2 2s2 2p3 N3- 7 + 3 = 10 1s2 2s2 2p6 O 8 1s2 2s2 2p4 O2- 8 + 2 = 10 F 9 1s2 2s2 2p5 F- 9 + 1 = 10 Ne 10 Na 11 1s2 2s2 2p6 3s1 Na+ = 10 Mg 12 1s2 2s2 2p6 3s2 Mg2+ = 10 Al 13 1s2 2s2 2p6 3s2 3p1 Al3+ = 10 Si 14 1s2 2s2 2p6 3s2 3p2 Si4+ = 10 P 15 1s2 2s2 2p6 3s2 3p3 P3- = 18 1s2 2s2 2p6 3s2 3p6 S 16 1s2 2s2 2p6 3s2 3p4 S2- = 18 Cl 17 1s2 2s2 2p6 3s2 3p5 Cl- = 18 Ar 18
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2. Valence number of electrons in the outermost shell
Figure 2.5 2. Valence number of electrons in the outermost shell 3. Electronegativity degree of attraction for electrons
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III. Molecular Chemistry
A. Definition B. Chemical Bonds 1. Definition (how atoms interact) 2. Types a. Electron Sharing i. Covalent bonds Non-polar (equal sharing of e-) Polar (unequal sharing of e-) Figure 2.6
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Table 2.6
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ii. Ionic (giving and receiving electrons)
Figure 2.7A Figure 2.7B
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b. Hydrogen Sharing Molecules sharing a hydrogen atom Figure 2.8
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b. Hydrogen Sharing Molecules sharing a hydrogen Figure 2.8
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c. Charge Sharing Molecules sharing a charge i. van der Waals Forces
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C. Formulas & Models 1. Why Important? (explains structure to function) 2. Types a. Molecular (atom ratio) b. Empirical (simplest ratio) c. Structural (actual shape)
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IV. Chemical Reactions A. Definition (how they react and why) B. Types
1. Synthesis, Dehydration, or Anabolic 2. Decomposition, Hydrolytic, or Catabolic 3. Exchange A(OH) + B(H) AB + H2O AB + H2O A(OH) + B(H) AB + CD AC + BD
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C. Factors Affecting Rates
3. ??? 2. ??? 1. Concentration 4. Others?
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V. Inorganic Molecules A. Water 1. Properties c. H-bonding a. States
b. Polar Figure 2.6 Figure 2.8 d. Density e. Cohesive Forces Figure 2.12 Figure 2.10
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2. Uses b. Temperature Stabilizer or Regulator a. Solvent Figure 2.11
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B. Salts 1. Properties (combining two nonmetals by ionic bond, make ions in solution) 2. Uses (Potential energy and move water)
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C. Acids, Bases, pH, & Buffers
1. Definitions a. An acid (increases the hydrogen ion concentration) H2CO3 HCO3- + H+ (Carbonic) H2SO4 H+ + H+ + SO4 2- (Sulfuric) HCl H+ + Cl- (Hydrochloric) b. A base (decreases the hydrogen ion concentration) HCl + NaOH NaCl + H2O (Sodium Hydroxide)
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d. A buffer (regulates the pH of a solution)
c. pH Scale (measures the hydrogen ion concentration) Figure 2.14 d. A buffer (regulates the pH of a solution) HCO3- + H+ H2CO3 HPO4-2 + H+ H2PO4- NH3 + H+ NH4+ 2. Uses & Misuses Why and how does acid precipitation affect vegetation?
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