1. Forensic Science International
Two thiazolylindoles and a benzimidazole: Novel compounds on the designer drug market with potential cannabinoid receptor activity 
Folker Westphal, Frank D. Sönnichsen, Siegfried Knecht, Volker Auwärter, Laura Huppertz 
Forensic Science International 
Volume 249, Pages (April 2015)
DOI: /j.forsciint
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2. Fig. 1 EI-MS spectrum (top) and CI-MS spectrum of 1 (bottom).
Forensic Science International  , DOI: ( /j.forsciint )
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3. Fig. 2 EI-MS spectrum (top) and CI-MS spectrum of 2 (bottom).
Forensic Science International  , DOI: ( /j.forsciint )
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4. Fig. 3
Acquired and simulated LC-HRMS-spectrum of compound 1 with suggested molecular formulae (SmartFormula).
Forensic Science International  , DOI: ( /j.forsciint )
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5. Fig. 4
Extracted chromatogram traces of C23H34N3OS and C23H34N3O3, illustrating the presence of one sulfur atom instead of two oxygens.
Forensic Science International  , DOI: ( /j.forsciint )
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6. Fig. 5
Acquired and simulated LC-HRMS-spectrum of compound 2 with suggested molecular formulae (SmartFormula).
Forensic Science International  , DOI: ( /j.forsciint )
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7. Fig. 6
Extracted chromatogram traces of C21H30N3S and C21H30N3O2, illustrating the presence of one sulfur atom instead of two oxygens.
Forensic Science International  , DOI: ( /j.forsciint )
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8. Fig. 7
bbCID spectrum and extracted chromatographic traces of compound 1 and its fragments with suggested molecular formulae (SmartFormula). Signals not deriving from the precursor are not annotated (non-parallel EICs). EICs of and are not illustrated due to their relatively low intensity.
Forensic Science International  , DOI: ( /j.forsciint )
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9. Fig. 8
bbCID spectrum and extracted chromatographic traces of compound 2 and its fragments with suggested molecular formulae (SmartFormula). Signals not deriving from the precursor are not annotated (non-parallel EICs).
Forensic Science International  , DOI: ( /j.forsciint )
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10. Fig. 9 IR spectrum of 1 (top) and detail (bottom).
Forensic Science International  , DOI: ( /j.forsciint )
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11. Fig. 10 IR spectrum of 2 (top) and detail (bottom).
Forensic Science International  , DOI: ( /j.forsciint )
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12. Fig. 11
NMR assignments of N-(2-methoxyethyl),N-iso-propyl-2-(1-pentyl-1H-indol-3-yl)-4-thiazolemethanamine(1). s: singlet; d: doublet t: triplet; q: quartet; p: pentet; sept: septet; m: multiplet.
Forensic Science International  , DOI: ( /j.forsciint )
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13. Fig. 12
NMR assignments of N,N-diethyl-2-(1-pentyl-1H-indol-3-yl)-4-thiazolemethanamine(2), abbreviations for multiplicities of 1H signals see Fig. 11.
Forensic Science International  , DOI: ( /j.forsciint )
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14. Fig. 13
Possible fragmentation pathways for m/z 213, 227 and 283 after CI/ESI.
Forensic Science International  , DOI: ( /j.forsciint )
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15. Fig. 14
3-([1,3]-thiazol-2-yl)indoles with CB1 receptor activity according to [16–18].
Forensic Science International  , DOI: ( /j.forsciint )
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16. Fig. 15 EI-MS spectrum (top) and CI-MS spectrum of 6 (bottom).
Forensic Science International  , DOI: ( /j.forsciint )
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17. Fig. 16
Acquired and simulated spectrum of compound 6 after LC-HRMS with suggested molecular formulae (SmartFormula).
Forensic Science International  , DOI: ( /j.forsciint )
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18. Fig. 17
bbCID spectrum and extracted chromatographic traces of compound 6 and its fragments with suggested molecular formulae (SmartFormula). Signals not deriving from the precursor are not annotated (non-parallel EICs).
Forensic Science International  , DOI: ( /j.forsciint )
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19. Fig. 18 IR spectrum of 6 (top) and detail (bottom).
Forensic Science International  , DOI: ( /j.forsciint )
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20. Fig. 19
NMR assignments of 1-(cyclohexylmethyl)-2-[(4-ethoxyphenyl)methyl]-N,N-diethyl-1H-benzimidazol-5-carboxamide(6), AB: AB-system; br: broad; other abbreviations for multiplicities of 1H signals see Fig. 11.
Forensic Science International  , DOI: ( /j.forsciint )
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