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Aim: What are acids and bases?
Do Now: List whatever you know about acids and bases.
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Acids Acids can be strong or weak electrolytes in aqueous solutions.
Acids (ex: HCl) react with certain metals to produce H2(g). Acids cause color changes in acid-base indicators: Blue litmus paper turns red in an acid Phenolphthalein is colorless in an acid Acids have a sour taste Table K has a list of Common Acids
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Bases Bases can be strong or weak electrolytes in aqueous solutions
Bases cause color changes in acid-base indicators: Red litmus paper turns blue in a base Phenolphthalein is pink in a base Bases feel slippery and taste bitter. Table L has a list of Common Bases
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Arrhenius Acid An Arrhenius acid gives off H+ (hydrogen ions) in aqueous solutions. Ex: HCl, HBr, H2SO4 The H+ in solution attaches to H2O to form H3O+ (hydronium ion). HCl + H2O H+ + Cl- + H2O Cl- + H3O+
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Arrhenius Base An Arrhenius base has OH and give off OH- (hydroxide ions) in an aqueous solution. Ex: NaOH, KOH, Ca(OH)2 NaOH Na+ + OH- Group 1 metals react with water to produce bases. 2Na(s) + 2H2O(l) 2 NaOH(aq) +H2(g)
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Question 1 Which substance can be classified as an Arrhenius acid? HCl
NaCl LiOH KOH
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Question 2 Which substance can be classified as an Arrhenius base? HCl
NaOH LiNO3 KHCO3
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Question 3 According to the Arrheneius theory, a substance that is classified as an acid will always yield H+(aq) NH+4(aq) OH-(aq) CO32-(aq)
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Bronsted-Lowry Acids and Bases
An acid is an H+ donor(proton donor). A base is an H+ acceptor (proton acceptor) HCl(g) H2O(l) H3O+(aq) Cl-(aq) HCl is an acid because it donates an H+ to the H2O. Accepts H+ ACID BASE Donates H+
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Bronsted-Lowry Acids and Bases
NH3(aq) H2O(l) NH4+(aq) + OH-(aq) NH3 is a base because it accepts an H+ from the H2O. Accepts H+ ACID BASE Donates H+
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Bronsted-Lowry Acids and Bases
Water can either be a proton donor (acid) or a proton acceptor (base); water is amphoteric.
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Question 4 According to the Bronsted-Lowry theory, a chloride ion (Cl-), acts as a base when it combines with An OH- ion A K+ ion An H- ion An H+ ion
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Question 5 According to the Bronsted-Lowry theory, an acid is
A proton donor, only A proton acceptor, only A proton donor and a proton acceptor Neither a proton donor nor a proton acceptor
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Conjugate acids and bases
NH3(aq) H2O(l) NH4+(aq) + OH-(aq) BASE ACID CONJUGATE CONJUGATE ACID BASE A conjugate base is what is remained after the acid gives up H+. A conjugate acid is what is formed when a base accepts a proton.
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Question 6 In the reaction H2PO4- + H2O H3PO4 + OH-
which pair represents an acid and its conjugate base? H2O and H2PO4- H2O and H3PO4 H3PO4 and OH- H3PO4 and H2PO4-
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Question 7 Given the reaction at equilibrium
HSO4- + H2O H3O+ + SO42- According to the Bronsted-Lowry theory, the two bases are H2O and H3O+ H2O and SO42- H3O+ and H2SO4- H3O+ and SO42-
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Summary Arrhenius Bronsted-Lowry Arrhenius Bronsted-Lowry
Acids Bases Arrhenius Gives off H+ in in water Bronsted-Lowry H+ donor Arrhenius Gives of OH- in water Bronsted-Lowry H+ acceptor
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