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Notes Chapter 9 Book chapter 7
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9-1 Nature of Solutions Video #17(solutions: CC) *Solution: p229 homo mixture in which one subst is dissolved in another subst ”Well mixed”
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-Properties of Solution
-2 parts make up a solution *Solute: subst that is dissolved *Solvent: the subst that does the dissolving
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-the solvent is usually a liquid
ex: water(aqueous solution) *Tincture: when alcohol is the solvent in the solution
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-more properties of solutions
Partic are indiv atoms, ions, or molecules Liquid solution appears clear
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3. Cannot be easily separated by simple means such a filtering
4. Solute molecules are evenly spread among solvent molecules(all parts are ident)
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-Conductivity of Solutions
-good conductor if it contains ions -nonconductor if it does not contain ions *Dissociation: separation of ions from a cmpnd during solution
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*Electrolytes: aqueous solution that conducts electricity -usually ionic cmpnds *Nonelectrolytes: not conduct ele -usually covalent cmpds
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*Ionization: formation of ions from solute molecules by the action of a solvent
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-Model of the solution process
Solute part are separated from the surface of the solid solute(Dissolving) -endothermic(takes up nrg)
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2. Solvent molecules are moved apart to allow solute molecules to enter the liquid surrounding the solid solute -endothermic
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3. Solute molecules are attracted to solvent molecules
-exothermic
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9-2 Making Solutions
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-Types of Solutions *miscible: 2 liquids that dissolve in each other
ex: water and alcohol -alloy: solutions of solids in solids
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-Rate of Solution -Ways to increase the rate of dissolving the solute – pp236 1. Heat it 2. Stir it 3. Crush it
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-Solubility -Measure of how much of a solute can be dissolved in a given amnt of solvent under certain conditions pp239
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-Solubility -solubility depends on the nature of the solute and solvent
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-Solubility -it is the mass of solute that can be dissolved in a definite amnt of solvent at a spcfc temp -factors that effect solubility 1.Temp 2. Pressure
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-temp ~solubility is increased in solids when temp is raised ~solubility is decreased in gases when temp is raised
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How much Sodium Chloride can be dissolved at 80 degrees Celsius?
40 grams If I want to dissolve 100 grams of Potassium Nitrate, how hot will the solvent need to be? 57 degrees Celsius
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ex: graph demo -pressure ~solid and liquid practically no effect ~gases dissolved in liquids, higher pressure higher solubility; and vise versa
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*Effervescence: escape of gas from a liquid solution
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-Concentration of Solutions pp240
*amnt of solute dissolved in a certain amnt of solvent *Concentrated: much solute *Dilute: little solute -also can be described as saturated, unsaturated, supersat
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1. Saturated Solutions *contains all the solute it can possibly hold at a given temp -temp must always be given
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2. Unsaturated Solution *contains less solute than it can possibly hold at a given temp
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3. Supersaturated Solution
*holds more solute than is normal for that temp. -supersat solu: is unstable
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9-3 Water-The Universal Solvent
-most common subst on earth -65% of body mass *Insoluble: will not dissolve
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-Structure of a Water Molecule
-unequal sharing produces an uneven charge *Polarity: oppositely charged ends
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-Polar and Nonpolar Molecules
-Like dissolves Like EX: Water Molecule Structure on board ex: p683
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-Water Quality -the taste, odor, and appearance of water determines its quality *Hard water: contains large amnts of dissolved metal ions *Soft water: no metal ions
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-Special Properties of Solutions
-when a solute is dissolved in a liquid solvent, the freezing pnt is lowered/boiling pnt raises *Freezing pnt depression: *Boiling pnt elevation:
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9-4 Suspensions and Colloids
Video #18(solution, suspen, coll) -physical prop determine whether a mixture is a suspension or a colloid
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-solute part are larger than atoms, ions, or molecules
Suspension: p456 hetero mixture -solute part are larger than atoms, ions, or molecules -part. large enough to be seen without a microscope -will settle out over time
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*Colloids: p455 homo mixture -not true solution -part. to small to be seen -does not separate -does scatter light
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*Brownian Motion: constant movement of colloid particles
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9-5 Acids -properties 1.pH below 7 2.taste sour
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3.turns blue litmus paper red
4.reacts with metals to produce H gas 5.ionizes in water to produce H+ 6.proton donor
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*Indicators: show definite color change when mixed with an acid ex: litmus, phenolphtalein *Hydronium ion H3O+: H+&water molecule
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-Common Acids -Strong acids HCl H2SO4 HNO3
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-Common Acids -Weak acids H2CO3 H3BO3 HC2H3O2
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9-6 Bases -properties 1.taste bitter 2.slippery to touch
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9-6 Bases 3.turn litmus from red to blue 4.turn phenolphthalein pink 5.dissolve fats and oils 6.contain hydroxide ions(OH-)
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9-7 Acids and Bases in Sol.: Salts
*pH: measure of the hydronium ion (H3O) -indicates how acidic the solution is
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9-7 Acids and Bases in Sol.: Salts
- 0<7 = acid - 7>14 = base - 7 = neutral
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-Determining Solution pH
-by using an indicator ex: pH, litmus, phen, methyl orange, bromthyol blue
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-Formation of Salts acid + base -> salt + water *neutralization:
*precipitate: a solid *precipitation: process of forming a solid Is a 2Bl replacement rxn
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