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Counting #’s vs. Measured #’s
Counting numbers – when we can exactly count the # of objects and there is no UNCERTAINTY in the values Example: Exactly 29 students in the room, no question about fractions of a person MEASURED NUMBERS – ALWAYS INVOLVE AN ESTIMATE WITH AN UNCERTAINTY IN THE LAST MEASURED DIGIT Example: The # of digits in your height depends on how many marks on the ruler Person’s height with different rulers: 174 cm vs cm
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Uncertainty in a Measurement
Uncertainty – Range of possible error Example: g g Means the true value lies within range g g g Link to uncertainty animation
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Definition of Significant Digits:
Digits in a measurement that are meaningful given the accuracy of the measuring device All of the places in a measurement that are certain plus 1 estimated place.
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IMPORTANCE OF SIGNIFICANT DIGITS
The conclusions that you can draw from data cannot exceed the accuracy your measuring device can actually measure Example: In Colorado, Blood alcohol of 0.08% = DUI If a breathalyzer with uncertainty of .01% were used → potentially big legal problem!
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Importance of Sig Fig’s cont.
If arrested person’s value = 0.08% % → means range of true values is: 0.07% (INNOCENT) 0.08 % (GUILITY) 0.09% (GUILITY) In practice, reduce # of ambiguous results by using more accurate instrument e.g. uncertainty of %
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Rules for Recording Significant Figures
Digital Electronic Device – record all of the numbers exactly as they appear on the screen. Example: Screen reads: g Record: g Uncertainty = g Incorrect: 1000 g Implies uncertainty is + 1 g
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RULES FOR RECORDING SIGNIFICANT FIGURES IN A NON-DIGITAL DEVICE
DETERMINE THE SMALLEST MARKED UNIT ESTIMATE ONE PLACE TO THE RIGHT OF THE SMALLEST MARKED UNIT EXAMPLE: Smallest marked unit = .1 cm → Estimate to nearest .01 3 4 5 centimeters a b c
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Reading a Meniscus Read at eye-level, from the bottom of the meniscus
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Rules for Interpreting Significant Figures In a Recorded Measurement
When is a Significant Figure NOT Significant? Answer: When it is a space-holding zero!
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Significant Figure Rules – Zero’s as Space-holders
It is sometimes necessary to insert zero to locate a decimal even though a place has not been accurately measured. Example: Newspaper Headline: 500,000 ATTEND FREE CONCERT IN CENTRAL PARK In reality, this # is an estimate, the exact # of people who attended is unknown
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Zero’s as spaceholders
Can’t report # as 5_ _ _ _ _ _ Can’t report # as 5 (very different than ½ million!) Convention: Use zero’s to take help locate decimals even though we haven’t actually measured those places
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Rules for Significant Digits
COUNTING # - numbers whose values are exactly known with no estimate. Significant figure rules don’t apply Example: 7 calculators = infinite number of significant figures (rules don’t apply, write down as many places as you want) Nonzero digits – ALWAYS significant Example: mL = 4 sig fig.
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LEADING ZERO’S LEADING – 0’s in front of all nonzero digits
LEADING ZERO’S are NEVER SIGNIFICANT Example: Weigh object in grams: 9.67 g (3 SF) Convert mass to kg by dividing measurement by 1000: 9.67 g (3 SF) → kg (Still 3 SF) Accuracy of balance didn’t change; still 3 SF
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CAPTIVE ZERO’S CAPTIVE ZERO’S – 0’s between nonzero digits.
Example: g (3 SF) CAPTIVE ZERO’S are ALWAYS SIGNIFICANT.
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TRAILING ZERO’S TRAILING ZERO’S – 0’s at the end of a number (i.e. to the right of all nonzero digits) Example: 100 mL TRAILING ZERO’S ARE NOT SIGNIFICANT UNLESS MARKED BY A DECIMAL. Examples: 100 mL = 1 SF; mL = 3 SF 1 x 102 mL = 1 SF; 1.0 x 102 mL = 2 SF; 1.00 x 102 mL = 3 SF
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Conversion Factors CONVERSION FACTORS – exact definitions → infinite number of significant figures In conversion problems: final SF in calculation match = SF original measurement Example: 6.0 in ( 2 sig figures) → convert to feet → final answer 2 sig figures 6.0 in feet = feet (2 SF) 12 in
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SIG FIGURE’S RULE SUMMARY
COUNTING #’S and Conversion factors – INFINITE NONZERO DIGIT’S: ALWAYS ZERO’S: LEADING : NEVER CAPTIVE: ALWAYS TRAILING :SOMETIMES Decimal present? YES; SIGNIFICANT NO; NOT SIGNIFICANT
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Significant Figures Problem Set HW 4-
1a) g ANS: 4 SF (all nonzero digits) 1b) g ANS: 5 SF (captive zero is significant) 1c) 3 pencils ANS: Counting # (infinite sig fig’s, sig. fig rules do not apply) 1d) lb ANS: 3 SF ; lb (leading zero are never significant)
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Significant Figures Problem Set HW 4-
1e) 300 kg ANS: 1 SF ; 300 (trailing zero, no decimal) 1f) 300. kg 1f) ANS: 3 SF; 300. kg ; (trailing zero with decimal) g 1g) ANS: 3 SF; g (leading zeros)
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Significant Figures Problem Set HW 4-
1h) cm 1h) ANS: 5 SF; (trailing zero with decimal are significant) 1i) mg ANS: 4 SF; (leading zero not significant, trailing zero with decimal are) 1j) x 103 m ANS: 4 SF; x 103 (trailing zero is significant, only first number between in scientific determines SF).
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