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Mr. Matthew Totaro Legacy High School Honors Chemistry

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1 Mr. Matthew Totaro Legacy High School Honors Chemistry
Chemical Bonding Mr. Matthew Totaro Legacy High School Honors Chemistry

2 "Perhaps one of you gentlemen would mind telling me just what it is outside the window that you find so attractive...?"

3 Bonding Theories Bonding is the way atoms attach to make molecules.
A chemical bond occurs when valence electrons are either transferred or shared between the nuclei of two atoms.

4 Sodium to Chlorine Bond
Chemical Bonds Sodium to Chlorine Bond

5 Types of Bonds

6 Types of Bonds We can classify bonds based on the kinds of atoms that are bonded together Types of Atoms Type of Bond Bond Characteristic metals to nonmetals Ionic electrons transferred nonmetals to Covalent shared metals Metallic pooled

7 Bond Polarity The larger the difference in how strong one atom pulls on the valence electrons, the more polar the bond is. Negative end toward more stronger atom. d+ H — F d-

8 Bond Polarity Bonding between unlike atoms results in unequal sharing of the electrons. One atom pulls the electrons in the bond closer to its side. One end of the bond has larger electron density than the other. The result is bond polarity. The end with the larger electron density gets a partial negative charge and the end that is electron deficient gets a partial positive charge. H Cl d+ d-

9 Bond Polarity Nonpolar (Pure) Covalent Bond e- are shared equally
symmetrical e- density usually identical atoms

10 + - Bond Polarity Polar Covalent Bond e- are shared unequally
asymmetrical e- density results in partial charges (dipole) + -

11 Bond Polarity Nonpolar Polar Ionic .

12 Electronegativity Measure of the pull an atom has on bonding electrons. Increases across the period (left to right). Decreases down the group (top to bottom). The larger the difference in electronegativity, the more polar the bond. Negative end toward more electronegative atom. d+ H — F d-

13 Electronegativity, Continued
2.1 1.0 0.9 0.8 0.7 1.5 1.2 1.3 1.1 1.4 1.6 1.8 1.7 1.9 2.2 2.4 2.0 2.5 3.0 3.5 4.0 2.8

14 Electronegativity, Continued

15 Electronegativity and Bond Polarity
If the difference in electronegativity between bonded atoms is 0 to 0.49, the bond is pure (nonpolar) covalent. If the difference in electronegativity between bonded atoms 0.5 to 1.7, the bond is polar covalent. If the difference in electronegativity between bonded atoms larger than 1.7, the bond is ionic. 15

16 Bond Polarity 3.0-3.0 = 0.0 3.0-2.1 = 0.9 3.0-1.0 = 2.0 Covalent Ionic
Nonpolar Polar 0.49 1.7 4.0 Electronegativity difference

17 Dipole Moments A dipole is a material with positively and negatively charged ends. Polar bonds or molecules have one end slightly positive, d+, and the other slightly negative, d-. Not “full” charges, come from nonsymmetrical electron distribution. Dipole moment, m, is a measure of the size of the polarity. Measured in debyes, D.

18 For Each of the Following Bonds, Determine Whether the Bond Is Ionic or Covalent. If Covalent, Determine if It Is Polar or Pure. If Polar, Indicate the Direction of the Dipole. Pb-O P-S Mg-Cl H-O

19 For Each of the Following Bonds, Determine Whether the Bond Is Ionic or Covalent. If Covalent, Determine if It Is Polar or Pure. If Polar, Indicate the Direction of the Dipole, Continued. Pb-O ( ) = 1.8 \ ionic. P-S ( ) = 0.4 \ nonpolar covalent. Mg-Cl ( ) = 1.8 \ ionic. H-O ( ) = 1.4 \ polar covalent.

20 Lewis Theory Lewis bonding theory emphasizes the importance of valence electrons. Uses dots to represent valence electrons either on or shared by atoms. Arranges bonding between atoms to attain certain sets of stable valence electron arrangements. G.N. Lewis ( )

21 Lewis Symbols of Atoms Li• Be• •B• •C• •N• •O: :F: :Ne:
Also known as electron dot symbols. Uses symbol of element to represent nucleus and inner electrons. Uses dots around the symbol to represent valence electrons. Puts one electron on each side first, then pair. Remember that elements in the same group have the same number of valence electrons; therefore, their Lewis dot symbols will look alike. Li• Be• •B• •C• •N• •O: :F: :Ne: ••

22 Lewis Symbols of Ions Cations have Lewis symbols without valence electrons. Lost in the cation formation. They now have a full “outer” shell that was the previous second highest energy shell. Anions have Lewis symbols with 8 valence electrons. Electrons gained in the formation of the anion. Li• Li+ :F: [:F:]− ••

23 Practice—Write the Lewis Symbol for Arsenic.

24 9.1

25 Octet Rule -atoms will tend to gain, lose, or share
electrons until their outer energy level contains eight electrons (or two like Helium) (Noble Gas e- configuration) -maximum stability

26                  +                                    sodium metal chlorine gas table salt

27 Lewis Bonding Theory Atoms bond because it results in a more stable electron configuration. Atoms bond together by either transferring or sharing electrons. Usually this results in all atoms obtaining an outer shell with 8 electrons. Octet rule. There are some exceptions to this rule—the key to remember is to try to get an electron configuration like a noble gas. Li and Be try to achieve the He electron arrangement.

28 Ionic Bonds Metal to nonmetal. Metal loses electrons to form cation.
Nonmetal gains electrons to form anion. Ionic bond results from + to − attraction. Lewis theory allows us to predict the correct formulas of ionic compounds.

29 Predict the formula of the compound that forms between
Example—Using Lewis Theory to Predict Chemical Formulas of Ionic Compounds Predict the formula of the compound that forms between calcium and chlorine. Cl Ca Draw the Lewis dot symbols of the elements. Cl Cl Transfer all the valance electrons from the metal to the nonmetal, adding more of each atom as you go, until all electrons are lost from the metal atoms and all nonmetal atoms have 8 electrons. Ca Ca2+ CaCl2

30 Practice—Use Lewis Symbols to Predict the Formula of an Ionic Compound Made from Reacting a Metal, Mg, that Has 2 Valence Electrons with a Nonmetal, N, that Has 5 Valence Electrons.

31 Practice—Use Lewis Symbols to Predict the Formula of an Ionic Compound Made from Reacting a Metal, M, that Has 2 Valence Electrons with a Nonmetal, X, that Has 5 Valence Electrons, Continued. Mg3N2

32 Covalent Bonds Often found between two nonmetals.
Atoms bonded together to form molecules. Strong attraction. Atoms share pairs of electrons to attain octets (or duets). Molecules generally weakly attracted to each other. Observed physical properties of molecular substance due to these attractions.

33 Single Covalent Bonds •• • •• • • • • •• •• •• •• •• •• F H O H F H O
Two atoms share one pair of electrons. 2 electrons. One atom may have more than one single bond. F •• •• H O H •• F •• •• H •• O •• H •• F

34 Double Covalent Bond •• • •• • ••
Two atoms sharing two pairs of electrons. 4 electrons. Shorter and stronger than single bond. O •• O •• O •• O

35 Triple Covalent Bond •• • •• • ••
Two atoms sharing 3 pairs of electrons. 6 electrons. Shorter and stronger than single or double bond. N •• N •• N •• N

36 Bonding and Lone Pair Electrons
Electrons that are shared by atoms are called bonding pairs. Electrons that are not shared by atoms but belong to a particular atom are called lone pairs. Also known as nonbonding pairs. O S O Bonding pairs •• •• •• Lone pairs ••

37 Lewis Structures for Covalent Compounds

38 Example: Write the Lewis structure of CO2.
Write down the given quantity and its units. Given: CO2 Build the Work area in this order: (1) “Write down ...”, (2) “Given:”. Bold text “SeO2 ” in the Example box, duplicate it, and float to the Given line. Make NEXT button hot. When NEXT button clicked, float the text from the Given lines in the Work area to the upper right Information Box, then clear the Work area.

39 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Write down the quantity to find and/or its units. Find: Lewis structure

40 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Design a solution map. Formula of compound Lewis structure Count and distribute electrons Skeletal structure

41 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Solution Map: formula → skeletal → electron distribution → Lewis Apply the solution map. Write skeletal structure. Least metallic atom central. H terminal. Symmetry.

42 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Solution Map: formula → skeletal → electron distribution → Lewis Apply the solution map. Count and distribute the valence electrons. Count valence electrons. 1A 8A 3A 4A 5A 6A 7A 2A C = 4 O = 2 ∙ 6 Total CO2 = 16 C O

43 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Solution Map: formula → skeletal → electron distribution → Lewis Apply the solution map. Count and distribute the valence electrons. Attach atoms. C = 4 O = 2 ∙ 6 Total CO2 = 16 Start = 16 e- Used = 4 e- Left = 12 e-

44 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Solution Map: formula → skeletal → electron distribution → Lewis Apply the solution map. Count and distribute the valence electrons. Complete octets. Outside atoms first. C = 4 O = 2 ∙ 6 Total CO2 = 16 Start = 16 e- Used = 4 e- Left = 12 e- Start = 12 e- Used = 12 e- Left = 0 e-

45 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Solution Map: formula → skeletal → electron distribution → Lewis Apply the solution map. Count and distribute the valence electrons. Complete octets. If not enough electrons to complete octet of central atom, bring in pairs of electrons from attached atom to make multiple bonds. Start = 12 e- Used = 12 e- Left = 0 e-

46 Example: Write the Lewis structure of CO2.
Information: Given: CO2 Find: Lewis structure Solution Map: formula → skeletal → electron distribution → Lewis Check: Start C = 4 e- O = 2 ∙ 6 e- Total CO2 = 16 e- The skeletal structure is symmetrical. All the electrons are accounted for. End Bonding = 4 ∙ 2 e- Lone pairs = 4 ∙ 2 e- Total CO2 = 16 e-

47 Writing Lewis Structures for Polyatomic Ions
The procedure is the same, the only difference is in counting the valence electrons. For polyatomic cations, take away one electron from the total for each positive charge. For polyatomic anions, add one electron to the total for each negative charge.

48 Example NO3─ 1. Write skeletal structure. 2. Count valence electrons.
N is central because it is the most metallic. 2. Count valence electrons. N = 5 O3 = 3∙6 = 18 (-) = 1 Total = 24 e-

49 Tro's Introductory Chemistry, Chapter 10
Example NO3─ , Continued 3. Attach atoms with pairs of electrons and subtract from the total. Electrons Start 24 Used 6 Left 18 N = 5 O3 = 3∙6 = 18 (-) = 1 Total = 24 e- Tro's Introductory Chemistry, Chapter 10 49

50 Example NO3─ , Continued 3. Complete octets, outside-in.
Keep going until all atoms have an octet or you run out of electrons. N = 5 O3 = 3∙6 = 18 (-) = 1 Total = 24 e- Electrons Start 24 Used 6 Left 18 Electrons Start 18 Used 18 Left 0

51 Example NO3─ , Continued 5. If central atom does not have octet, bring in electron pairs from outside atoms to share. Follow common bonding patterns if possible.

52 Example HNO3 1. Write skeletal structure. 2. Count valence electrons.
Since this is an oxyacid, H on outside attached to one of the Os; N is central. 2. Count valence electrons. N = 5 H = 1 O3 = 3∙6 = 18 Total = 24 e-

53 Tro's Introductory Chemistry, Chapter 10
Example HNO3 , Continued 3. Attach atoms with pairs of electrons and subtract from the total. N = 5 H = 1 O3 = 3∙6 = 18 Total = 24 e- Electrons Start 24 Used 8 Left 16 Tro's Introductory Chemistry, Chapter 10 53

54 Example HNO3 , Continued 4. Complete octets, outside-in.
H is already complete with 2. 1 bond. Keep going until all atoms have an octet or you run out of electrons. N = 5 H = 1 O3 = 3∙6 = 18 Total = 24 e- Electrons Start 24 Used 8 Left 16 Electrons Start 16 Used 16 Left 0

55 Example HNO3 , Continued 5. If central atom does not have octet, bring in electron pairs from outside atoms to share. Follow common bonding patterns if possible.

56 Practice—Lewis Structures
NClO H3BO3 NO2-1 H3PO4 SO3-2 P2H4 Tro's Introductory Chemistry, Chapter 10 56

57 Practice—Lewis Structures, Continued
NClO H3BO3 NO2-1 H3PO4 SO3-2 P2H4 32 e- 18 e- 24 e- 26 e- 18 e- 14 e- Tro's Introductory Chemistry, Chapter 10 57

58 Exceptions to the Octet Rule
H and Li, lose one electron to form cation. Li now has electron configuration like He. H can also share or gain one electron to have configuration like He. Be shares two electrons to form two single bonds. B shares three electrons to form three single bonds. Expanded octets for elements in Period 3 or below. Using empty valence d orbitals. Some molecules have odd numbers of electrons. NO

59 Resonance

60 This is the Lewis structure we would draw for ozone, O3.
Resonance This is the Lewis structure we would draw for ozone, O3. + -

61 Resonance But this is at odds with the true, observed structure of ozone, in which… …both O—O bonds are the same length. …both outer oxygens have a charge of 1/2.

62 Resonance One Lewis structure cannot accurately depict a molecule such as ozone. We use multiple structures, resonance structures, to describe the molecule.

63 Drawing Resonance Structures
Draw first Lewis structure that maximizes octets. Move electron pairs from outside atoms to share with central atoms. If central atoms, 2nd row, only move in electrons, you can move out electron pairs from multiple bonds.

64 Practice—Draw Lewis Resonance Structures for CNO− (C Is Central with N and O Attached)
64

65 Practice—Draw Lewis Resonance Structures for CNO− (C Is Central with N and O Attached), Continued
(-) = 1 Total = 16 e- 65

66 Molecular Geometry

67 Molecular Shapes The shape of a molecule plays an important role in its reactivity. By noting the number of bonding and nonbonding electron pairs we can easily predict the shape of the molecule.

68 What Determines the Shape of a Molecule?
Simply put, electron pairs, whether they be bonding or nonbonding, repel each other. By assuming the electron pairs are placed as far as possible from each other, we can predict the shape of the molecule.

69 This molecule has four electron domains.
We can refer to the electron pairs as electron domains. In a double or triple bond, all electrons shared between those two atoms are on the same side of the central atom; therefore, they count as one electron domain. This molecule has four electron domains.

70 Valence Shell Electron Pair Repulsion Theory (VSEPR)
“The best arrangement of a given number of electron domains is the one that minimizes the repulsions among them.”

71 Electron-Domain Geometries
These are the electron-domain geometries for two through six electron domains around a central atom.

72 Electron-Domain Geometries
All one must do is count the number of electron domains in the Lewis structure. The geometry will be that which corresponds to that number of electron domains.

73 Molecular Geometries The electron-domain geometry is often not the shape of the molecule, however. The molecular geometry is that defined by the positions of only the atoms in the molecules, not the nonbonding pairs.

74 Molecular Geometries Within each electron domain, then, there might be more than one molecular geometry.

75 Linear Electron Domain
In this domain, there is only one molecular geometry: linear. NOTE: If there are only two atoms in the molecule, the molecule will be linear no matter what the electron domain is.

76 Trigonal Planar Electron Domain
There are two molecular geometries: Trigonal planar, if all the electron domains are bonding Bent, if one of the domains is a nonbonding pair.

77 Tetrahedral Electron Domain
There are three molecular geometries: Tetrahedral, if all are bonding pairs Trigonal pyramidal if one is a nonbonding pair Bent if there are two nonbonding pairs

78 Trigonal Bipyramidal Electron Domain
There are four distinct molecular geometries in this domain: Trigonal bipyramidal Seesaw T-shaped Linear

79 Octahedral Electron Domain
All positions are equivalent in the octahedral domain. There are three molecular geometries: Octahedral Square pyramidal Square planar

80 Practice—Predict the Shape Around the Central Atom
ClO2− H3BO3 NO2-1 H3PO4 SO32− P2H4 80

81 Practice—Predict the Shape Around the Central Atom, Continued
ClO2− H3BO3 NO2-1 H3PO4 SO32− P2H4 Bent Tetrahedral Trigonal Planar Trig. pyramidal Bent Trig. pyramidal 81

82 Molecular Polarity 82

83 Polarity of Molecules In order for a molecule to be polar it must:
1. Have polar bonds. Electronegativity difference—theory. Bond dipole moments—measured. 2. Have an asymmetrical shape. Vector addition. Polarity effects the intermolecular forces of attraction.

84 Molecule Polarity The O—C bond is polar. The bonding electrons are pulled equally toward both O ends of the molecule. The net result is a nonpolar molecule. 84

85 Molecule Polarity, Continued
The H—O bond is polar. Both sets of bonding electrons are pulled toward the O end of the molecule. The net result is a polar molecule. 85

86 Example—Determining if a Molecule Is Polar
86

87 Determine if NH3 is polar.

88 Example: Determine if NH3 is polar.
Write down the given quantity and its units. Given: NH3 Build the Work area in this order: (1) “Write down ...”, (2) “Given:”. Bold text “SeO2 ” in the Example box, duplicate it, and float to the Given line. Make NEXT button hot. When NEXT button clicked, float the text from the Given lines in the Work area to the upper right Information Box, then clear the Work area.

89 Example: Determine if NH3 is polar.
Information: Given: NH3 Write down the quantity to find and/or its units. Find: If polar

90 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Design a solution map. Formula of compound Molecular polarity Lewis structure Molecular shape Bond polarity and

91 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Draw the Lewis structure. Write skeletal structure.

92 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Draw the Lewis structure. Count valence electrons. N = 5 H = 3 ∙ 1 Total NH3 = 8

93 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Draw the Lewis structure. Attach atoms. N = 5 H = 3 ∙ 1 Total NH3 = 8 Start 8 e- Used 6 e- Left 2 e-

94 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Draw the Lewis structure. Complete octets. N = 5 H = 3 ∙ 1 Total NH3 = 8 ∙∙ Start 2 e- Used 2 e- Left 0 e-

95 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Determine if bonds are polar. Electronegativity N = 3.0 H = 2.1 ∙∙ 3.0 – 2.1 = 0.9  polar covalent

96 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Determine shape of molecule. 4 areas of electrons around N; 3 bonding areas 1 lone pair ∙∙ Shape = trigonal pyramid

97 Example: Determine if NH3 is polar.
Information: Given: NH3 Find: If polar Solution Map: formula → Lewis → polarity and shape → molecule polarity Apply the solution map. Determine molecular polarity. Bonds = polar Shape = trigonal pyramid Molecule = polar

98 Practice—Decide Whether Each of the Following Molecules Is Polar
EN O = 3.5 N = 3.0 Cl = 3.0 S = 2.5 99

99 Practice—Decide Whether the Each of the Following Molecules Is Polar, Continued
Trigonal bent Cl N O 3.0 3.5 Trigonal planar O S 3.5 2.5 1. Polar bonds, N—O 2. Asymmetrical shape 1. Polar bonds, all S—O 2. Symmetrical shape Polar Nonpolar 100

100 Molecular Polarity Affects Solubility in Water
Polar molecules are attracted to other polar molecules. Since water is a polar molecule, other polar molecules dissolve well in water. And ionic compounds as well. Some molecules have both polar and nonpolar parts. 101

101 Properties of Substances
Ionic Bond

102 Properties of Substances
Metallic Bond

103 Properties of Substances
Covalent Bond

104 Molecular Solids Bond (Covalent) Nonmetal + Nonmetal Example
Ice Water, H2O Melting Point Low to moderate Conductivity Solid = no Liquid = no Aqueous = no Malleability brittle Water, H2O

105 Metallic Solids Bond (Metallic) Example Copper, Cu Melting Point
Metal + Metal Example Copper, Cu Melting Point Low to High Conductivity Solid = yes Liquid = yes Aqueous = yes Malleability malleable Copper metal, Cu

106 Ionic Solids Bond (Ionic) Example Table Salt, NaCl Melting Point High
Metal + Nonmetal Example Table Salt, NaCl Melting Point High Conductivity Solid = no Liquid = yes Aqueous = yes Malleability brittle Table Salt, NaCl

107 Covalent Network Solids
Bond (Covalent) Nonmetal + Nonmetal Example Diamond, C Melting Point Very High Conductivity Solid = no Liquid = no Aqueous = no Malleability Brittle, very hard


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