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The mole
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Molar Mass
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Recall The term “Avogadro’s Number” was coined by Jean Baptiste Perrin when he determined the number of atoms in one gram of atomic hydrogen And he figured out that 1 gram of hydrogen has 6.022x1023 atoms Remember: 6.022x1023 atoms = 1 mole Which means that 1 mole of hydrogen has a mass of 1 gram
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Recall Also remember that atomic mass is measured in atomic mass units (amu) 1 amu = 1/12 mass of a carbon atom Going back to Avogadro, based on Avogadro’s Law there are x1023 atoms in 12 grams of C-12 Basically, look at the number of amu on the periodic table = Number of grams per mole for that element
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Atomic Molar Mass (MM) MM of C = 12.01 g/mol
What is molar mass? The mass (g) of 1 mole of atoms of a particular element or molecule → The mass (g) of 6.02 X 1023 atoms or particles How do you figure out molar mass? Find on periodic table MM of H = g/mol MM of C = g/mol
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practice 14.01 g/mol 87.62 g/mol 55.85 g/mol 26.98 g/mol
What is the molar mass of the following elements? Nitrogen: Strontium: Iron: Aluminum: 14.01 g/mol 87.62 g/mol 55.85 g/mol 26.98 g/mol
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Calculations with Molar Mass
molar mass (g/mol) Mass (g) n (mol)
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practice 1 mol Al = 26.98g 3 mol Al = 26.98g x 3.00 = 80.9 g
Aluminum is often used for the structure of light-weight bicycle frames. How many grams of Al are in 3.00 moles of Al? 3.00 moles Al ? g Al 1 mol Al = 26.98g 3 mol Al = 26.98g x 3.00 = 80.9 g
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Everything must go through Moles!!!
Calculations molar mass (g/mol) Avogadro’s number (6.02 X 1023 particles/mole) mass (g) n (mol) particles Everything must go through Moles!!!
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Let’s combine it all!
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practice 𝑚𝑎𝑠𝑠 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 =# 𝑚𝑜𝑙𝑒𝑠 1 mol Cu = 63.546 g
How many atoms of Cu are present in 35.4 g of Cu? 1 mol Cu = g 6.023𝑥1023 𝑎𝑡𝑜𝑚𝑠 1 𝑚𝑜𝑙𝑒 = ?𝑎𝑡𝑜𝑚𝑠 𝑚𝑜𝑙𝑒𝑠 𝑔 𝐶𝑢 1 𝑚𝑜𝑙𝑒 = 35.4 𝑔 𝐶𝑢 ? 𝑚𝑜𝑙𝑒𝑠 ? = 3.35x1023 atoms ? = mol 𝑚𝑎𝑠𝑠 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 =# 𝑚𝑜𝑙𝑒𝑠 # 𝑚𝑜𝑙𝑒𝑠 𝑥 6.022𝑥 =# 𝑎𝑡𝑜𝑚𝑠
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practice 𝑚𝑎𝑠𝑠 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 =# 𝑚𝑜𝑙𝑒𝑠 1 mol K = 39.0983 g
How many atoms of K are present in 78.4 g of K? 1 mol K = g 6.023𝑥1023 𝑎𝑡𝑜𝑚𝑠 1 𝑚𝑜𝑙𝑒 = ?𝑎𝑡𝑜𝑚𝑠 2.00 𝑚𝑜𝑙𝑒𝑠 𝑔 𝐾 1 𝑚𝑜𝑙𝑒 = 78.4 𝑔 𝐾 ? 𝑚𝑜𝑙𝑒𝑠 ? = 1.25x1024 atoms ? = 2.00 mol 𝑚𝑎𝑠𝑠 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 =# 𝑚𝑜𝑙𝑒𝑠 # 𝑚𝑜𝑙𝑒𝑠 𝑥 6.022𝑥 =# 𝑎𝑡𝑜𝑚𝑠
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Molecular Molar Mass (MM)
Mass in grams of 1 mole equals the sum of the atomic masses H2 H20 2 x (MM of H) = 2(1.01g/mol) = 2.02g/mol (2 x (MM of H)) + (MM of O) = 2(1.01g/mol) + (16.00g/mol) = g/mol)
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Practice CH3OH Al2(SO4)3 (1 x MM of C) + (4 x MM of H) + (1 x MM of O)
= 12.01g/mol + (4 x (1.01g/mol) g/mol) = g/mol (2 x MM of Al) + (3 x MM of S) + (12 x MM of O) = (2 x 26.98g/mol) + (3 x (32.06g/mol) + (12 x16.00g/mol) = g/mol
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Ready for a challenge?
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practice 1)Prozac, C17H18F3NO, is a widely used antidepressant that inhibits the uptake of serotonin by the brain. Find its molar mass. (17 x MM of C) + (18 x MM of H) + (3 x MM of F) + (1 x MM of N) + (1 x MM of O) = (17 x 12.01g/mol) + (18 x 1.01g/mol) + (3 x19.00g/mol) + (1 x 14.01g/mol) + (1 x16.00g/mol) = g/mol
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The artificial sweetener aspartame (Nutra-Sweet) formula C14H18N2O5 is used to sweeten diet foods, coffee and soft drinks. How many moles of aspartame are present in 225 g of aspartame? Step 1 – Calculate molar mass (14 x MM of C) + (18 x MM of H) + (2 x MM of N) + (5 x MM of O) = (14 x 12.01g/mol) + (18 x 1.01g/mol) + (2 x 14.01g/mol) + (5 x16.00g/mol) = g/mol Step 2 – Calculate # moles 𝑚𝑎𝑠𝑠 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 =# 𝑚𝑜𝑙𝑒𝑠 = 225𝑔 𝑔/𝑚𝑜𝑙 = 𝑚𝑜𝑙
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= 180.18 g/mol = (6 x 12.01g/mol) + (12 x 1.01g/mol) + (6 x16.00g/mol)
What is the mass (in grams) of 1.20 X 1024 molecules of glucose (C6H12O6)? Step 1 – Calculate molar mass (6 x MM of C) + (12 x MM of H) + (6 x MM of O) = (6 x 12.01g/mol) + (12 x 1.01g/mol) + (6 x16.00g/mol) = g/mol Step 2 – Calculate # moles Step 3 – Calculate mass # 𝑎𝑡𝑜𝑚𝑠 6.022𝑥 =# 𝑚𝑜𝑙𝑒𝑠 𝑚𝑎𝑠𝑠=𝑛 𝑥 𝑀𝑀 = (1.99 mol)( g/mol) = 1.20𝑥 𝑥 10 23 = 1.99 𝑚𝑜𝑙 = 359𝑔
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= 32.00 g/mol # 𝑚𝑜𝑙𝑒𝑠 𝑥 6.022𝑥 10 23 =# 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠
How many molecules of oxygen gas, O2, are present in 78.1 g of O2? Step 1 – Calculate molar mass Step 3 – Calculate # molecules = (2 x MM of O) # 𝑚𝑜𝑙𝑒𝑠 𝑥 6.022𝑥 =# 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠 2.44 𝑥 6.022𝑥 =# 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑒𝑠 = (2 x16.00g/mol) =1.48 𝑥 6.023𝑥 10 24 = g/mol Step 2 – Calculate # moles 𝑚𝑎𝑠𝑠 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 =# 𝑚𝑜𝑙𝑒𝑠 = 78.1𝑔 𝑔/𝑚𝑜𝑙 = 2.44 𝑚𝑜𝑙
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