1. CHEM 106
The Periodic Table
Atoms/Elements
BONDS
Compounds/Molecules

2. Compounds & Chemical Bonds
Atoms in a compound (molecule) are in ratios of whole numbers with specific 3-dimensional arrangements due to attractive inter-atomic forces (Bonds). These bonds provide favorable energy states & spatial positions (lower energy & farther apart, but not too far, are better), which result in molecules having new chemical, physical, and biological properties.

3. Chemical Bonds

4. Electrons, Configurations, & Bonds Noble Gases and The Rule of Eight
When a nonmetal and a metal combine, they form an ionic bond: Valence electrons of the metal are lost and the nonmetal gains these electrons to achieve a Noble gas electron configuration.
When two nonmetals combine, they form a covalent bond: They share electrons to achieve a Noble gas electron configuration.

6. Periodic Properties

7. Periodic Table Properties & Organization

8. Periodic Table Properties & Organization

9. Number of Valence Electrons for Elements in the “A” lettered Vertical Columns Equal the Column Number
Notice 8A has no ions that form. These are the stable, “inert”, “Noble”, gases

10. Ionic Bonds
Result from electrostatic attractions of closely packed, oppositely charged ions.
Form when an atom which can easily lose electrons reacts with one which has a high electronegativity (electron affinity), that is, it can easily gain electrons.
Eg. Mg and Cl; K and O

11. Electron Configurations

12. Ionic Compounds Neutrally Charged Eg. Salt: NaCl  1 Na+ and 1 Cl -
What is the proportion of ions for a compound formed from Mg ion and chlorine?
Mg2+ and Cl
1 Mg2+ combines with 2 Cl
MgCl2

13. QUESTION
Predict the formula for the binary ionic compound formed by aluminum and oxygen.
A) Al2O3 B) Al3O2 C) Al2O D) AlO2

14. ANSWER
Predict the formula for the binary ionic compound formed by aluminum and oxygen.
A) Al2O3 B) Al3O2 C) Al2O D) AlO2
Correct Answer: A
Question Number: 5

15. Ionic vs. Covalent Bonding

16. Polyatomic Ions
These polyatomic species involve both ionic and covalent bonding.

17. Which formula containing polyatomic ions is correct?
QUESTION
Which formula containing polyatomic ions is correct?
A) MgNO3 B) NH4CO3 C) Na(PO4)3 D) Al2(SO4)3

18. Which formula containing polyatomic ions is correct?
ANSWER
Which formula containing polyatomic ions is correct?
A) MgNO3 B) NH4CO3 C) Na(PO4)3 D) Al2(SO4)3
Correct Answer: D
Question Number: 13

19. Electronegativity

20. Electronegativity

21. Figure: 08-06

22. QUESTION

23. ANSWER B) Rb < O < F
Electronegativities increase moving up a column
and to the right in the periodic table. .
HMCLASS PREP: Figure 8.3

25. QUESTION

26. ANSWER D) ionic bonds If two atoms have greatly differing
electronegativities the more electronegative
atom will pull on the bonding electrons so
strongly the electrons will transfer from one atom
to the other. .

27. Chemical Formulas & Molecular Representations

28. Structural Representations of Quinine

29. Proteins & Small Molecules
The interaction of a large protein bio-polymer, acetylcholinesterase, with a relatively small molecule of acetylcholine. A general process similar to the way that scientists that think we smell and many physiological processes.

30. Detecting stuff we cannot see: the Sense of Smell
Models, Theories & Interactions
Structure-Odor Relationships
Karen J. Rossiter, Chem. Rev., 1996, 96,

31. Historical view of a few smell receptors.
4 October 2004
The Nobel Assembly at Karolinska Institutet has today decided to award
The Nobel Prize in Physiology or Medicine for 2004
jointly to
Richard Axel and Linda B. Buck
for their discoveries of
"odorant receptors and the organization of the olfactory system"
They discovered a large gene family, comprised of some 1,000 different genes (three per cent of our genes) that give rise to an equivalent number of olfactory receptor types. These receptors are located on the olfactory receptor cells, which occupy a small area in the upper part of the nasal epithelium and detect the inhaled odorant molecules.

33. Shapes & Interactions: Mirror Images & Smell
S-(+)-d-
R-(-)-l-
S-(+)- caraway R-(-)- spearmint