1. Band Theory of Electronic Structure in Solids
Continuing with Chapter 11 (semiconductors)
Sections 11.4, 11.6, 11.7

2. Band Theory: “Bound” Electron Approach
For the total number N of atoms in a solid (1023 cm–3), N energy levels split apart within a width E.
Leads to a band of energies for each initial atomic energy level (e.g. 1s energy band for 1s energy level).
Two atoms
Six atoms
Solid of N atoms
Electrons must occupy different energies due to Pauli Exclusion principle.
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3. Conductors, Insulators, Semiconductors
NaCl is an insulator, with a band gap of 2 eV,
which is much larger than the thermal energy at
T=300K
Therefore, only a tiny fraction of electrons are
in the conduction band

4. Conductors, Insulators, Semiconductors
Silicon and germanium have band gaps of 1 eV and
0.7 eV, respectively. At room temperature, a small
fraction of the electrons are in the conduction
band. Si and Ge are intrinsic semiconductors

5. Intro to Semiconductors and p-n junction devices

6. Band Diagram: Insulator
Conduction band
(Empty)
T > 0 EC
Egap EF EV
Valence band
(Filled)
At T = 0, the lower valence band is filled with electrons and the upper conduction band is empty, leading to zero conductivity.
Fermi energy: EF is at midpoint of large energy gap (2-10 eV) between conduction and valence bands.

7. Band Diagram: Intrinsic Semiconductor
Conduction band
(Partially Filled) EC EF EV
Valence band
(Partially Empty)
At T = 0, lower valence band is filled with electrons and upper conduction band is empty, leading to zero conductivity.
Fermi energy EF is at midpoint of small energy gap (<1 eV) between conduction and valence bands.

8. Donor Dopant in a Semiconductor
For group IV Si, add a group V element to “donate” an electron and make n-type Si (more negative electrons!).
“Extra” electron is weakly bound, with donor energy level ED just below conduction band EC.
Dopant electrons easily promoted to conduction band, increasing electrical conductivity by increasing carrier density n.
Fermi level EF moves up towards EC. EC EV EF ED
Egap~ 1 eV
n-type Si

9. Band Diagram: Acceptor Dopant in Semiconductor
For Si, add a group III element to “accept” an electron and make p-type Si (more positive “holes”).
“Missing” electron results in an extra “hole”, with an acceptor energy level EA just above the valence band EV.
Holes easily formed in valence band, greatly increasing the electrical conductivity.
Fermi level EF moves down towards EV. EA EC EV EF
p-type Si

10. Dopant Density via Hall Effect
Why Useful? Determines carrier type (electron vs. hole) and carrier density n for a semiconductor.
How? Place semiconductor into external B field, push current along one axis, and measure induced Hall voltage VH along perpendicular axis.
Derived from Lorentz equation FE (qE) = FB (qvB).
Carrier density n = (current I) (magnetic field B)
(carrier charge q) (thickness t)(Hall voltage VH)
Hole
Electron
+ charge
– charge
Solid-State Physics

11. pn Junction: Band Diagram
pn regions “touch” & free carriers move
Due to diffusion, electrons move from n to p-side and holes from p to n-side.
Causes depletion zone at junction where immobile charged ion cores remain.
Results in a built-in electric field (103 to 105 V/cm), which opposes further diffusion.
Note: EF levels are aligned across pn junction under equilibrium.
n-type
electrons EC EF EF EV
holes
p-type
pn regions in equilibrium – – EC – – + – + – EF + + – – – + + + – – + + – + + + EV
Depletion Zone