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As always… Lon-Capa assignments Lecture videos Textbook Read
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Hess’s Law Due to first law and H being a state function.
If a reaction is reversed, the sign of H is also reversed The magnitude of ΔH is directly proportional to the quantities of reactants and products in a reaction. That is, if the coefficients in a balanced equation are multiplied by an integer, the value of H is multiplied by the same integer.
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2NaHCO3(s) Na2CO3(s) + CO2(g) + H2O(l)
Clicker Question Baking soda can decompose to produce sodium carbonate, carbon dioxide, and water according to the following chemical equation: 2NaHCO3(s) Na2CO3(s) + CO2(g) + H2O(l) Given the following data, determine ΔH° for the decomposition of baking soda as written above. Na2CO3(s) + 2HCl(aq) 2NaCl(aq) + CO2(g) + H2O(l) ΔH° = –28.9 kJ/mol NaHCO3(s) + HCl(aq) NaCl(aq) + CO2(g) + H2O(l) ΔH° = 28.3 kJ/mol a) –0.6 kJ b) kJ c) kJ d) kJ e) kJ
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Chapter 9: Problem #117 This problem is an application of Hess’s law, although it may not be obvious upon reading it.
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Clicker Question Using the following data, calculate the standard enthalpy of formation of the compound ICl(g), in kJ/mol: H° (kJ/mol) Cl2(g) 2Cl(g) 242.3 I2 (g) 2I(g) 151.0 ICl(g) I(g) + Cl(g) 211.3 I2(g) I2(s) –62.8 a) –14.6 b) – c) – d) e) 33.5
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Fe2O3(s) + 2Al(s) Al2O3(s) + 2Fe(l)
Clicker Question Given that ΔH°fusion for Fe(s) = 13.6 kJ/mol and the following data: Fe2O3(s) Al2O3(s) ΔHf°(kJ/mol) –826.0 –1676.0 Determine ΔH°rxn (kJ) for the thermite reaction (at constant temperature) as represented by the equation: Fe2O3(s) + 2Al(s) Al2O3(s) + 2Fe(l) a) – b) – c) – d) – e) –877.2
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