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Organic Chemistry POLYMERS
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A- Polymer A1. Poly = many A2. Mer = units
A3. Polymers are large molecules that has many units bonded together A4. The individual units made up the polymer are called monomers
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B- Natural Polymers Amylose (in starch) DNA
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B- Natural Polymers (Cont’d)
Protein
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C-Man-made or Synthetic Polymers
C1. Type 1: Addition polymers C2. Made by addition reaction of monomers that have double bonds or triple bonds
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D-Properties of Addition Polymers
D1. Stable as the double bond converted to single bond D2. Flexible, stretchable and mouldable thanks to lots of weak, intermolecular forces that hold the long polymer chain together
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D- Properties of Addition Polymers (Cont’d)
D3. Addition polymers can also cross-link with one another if extra double bonds are present D4. The more crosslinks occur, the more rigid the polymers
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E- Plastic bag- How it’s made???
E1. Made from a polymer called polyethylene E2. Take 1 million year to break down/ degrade a plastic bag E3. What do you think of our Toronto’s recent 5cent/plastic bag policy?
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E- Plastic bag- How it’s made???
Watch video
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F- Common Addition Polymers
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G- Another Man-made Addition Polymer
G1- The super absorbent polymer is Polyacrylic acid Video
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H- Super absorbent Polymer (Cont)
H1. absorb up to 1,000 g of water per gram of polymer
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I- Man-made or Synthetic Polymers (cont’d)
I1. Type 2: Condensation polymers I2. Made by condensation reaction in which monomers are joined and water is produced
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J- Natural condensation polymers
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K- Properties of Condensation Polymers
K1. Has the ability to hydrogen bonds thanks to the C=O groups K2. Thus making condensation polymer very strong K3. Kevlar: a polyamide, condensation polymer that is stronger than steel K4. Kelvar is used to make aircraft parts, sport equipment, protective clothing, bullet proof vests for policemen
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L- Hydrogen bonding in Condensation Polymers
L1. HYDROGEN BONDING IN PROTEINS L2. HYDROGEN BONDING IN Kevlar
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M- Some common condensation polymers
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N- Applications of Nylon
N1. Invented by Dupont N2. Nylon stands for New York & London N3. Tear resistant N4. Water-proof Used in making parachutes stocking sleeping bags tent, sail cooking utensils Nylon = New York and London where the research on Nylon was being done. Interesting.
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N- Nylon N5. Watch synthesis movie
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O- Silicone as polymer Silicone based baking pan
Traditional metal baking pan Silicone breast implant Silicone structure
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P- HomeWork review for Organic Chemistry Unit
# 5, 6, 9 (a,c,e,f,I,i to v), 10, 11, 12, page
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Q- POLYMER TIME! Making slime
Pour Elmer Glue to the mark in a plastic cup Add equal volume of water to dissolve the glue Add desire food colorant Stir Add prepared Borax solution DROPWISE until the slime is somewhat thicken Don’t add too much Borax
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