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A Reminder… assume ideal
We that we live in an world where: Gas particles have no mass Gas particles have no volume Gas particles have elastic collisions These assumptions are used when trying to calculate the AMOUNT of a gas we have!
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Why are these assumptions important?
PV = nRT Image source: thefreedictionary.com
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PV = nRT P V n R T The Ideal Gas Law RESSURE OLUME MOLES OF GAS
GAS CONSTANT EMPERATURE Image source: popartuk.com
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The MysteRious R 62.4 mmHg · L mol · K 8.31 kPa · L mol · K
R is a constant (doesn’t change). Number value of R depends on other units. Units of R are a combination of many units. 62.4 mmHg · L mol · K 8.31 kPa · L mol · K atm · L mol · K Image source: toysrus .com
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Ummm… What? PV = nRT P V R = n T (kPa) (mm Hg) (L) (atm) R = (mol) (K)
Solve for R: P V R = n T Plug in units: (kPa) (mm Hg) (L) (atm) R = (mol) (K)
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Gas Laws, Gas Laws Everywhere!
T1 = V2 T2 Charles' Law Boyle's Law P1 x V1 = P2 x V2 P1 V1 P2 V2 = T1 T2 Combined Gas Law Ideal Gas Law Used with CHANGING CONDITIONS P V = n R T Used with only ONE SET OF CONDITIONS
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When to Use PV = nRT Calculating amount of gas in moles
Calculating P, V, or T if moles of gas are known. IMPORTANT! We must have 3 out of 4 pieces of information: P V n T
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Practice with the Ideal Gas Law
A gas sample occupies 2.62 L at 285ºC and 3.42 atm. How many moles are present in this sample?
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But Let’s Be Practical…
We don’t usually measure in moles! We usually measure quantities in GRAMS! PV = nRT PVM = gRT
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PVM = gRT P V M g R T RESSURE OLUME OLAR MASS OF GAS (g/mol)
RAMS OF GAS GAS CONSTANT EMPERATURE Image source: popartuk.com
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Practice with the Ideal Gas Law
A balloon is filled with g of helium to a pressure of 1.26 atm. If the desired volume of the balloon is L, what must the temperature be in ºC?
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PV=nRT vs. PVM=gRT Use PV=nRT when: Use PVM=gRT when:
You are given moles in the problem. You are searching for moles as an answer. Use PVM=gRT when: You are given grams in the problem. You are searching for grams as an answer.
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