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Strengths of Acids and Bases
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Electrical Conductivity
Acidic and basic solutions conduct electricity. We can see a current being conducting by electrocuting a pickle. A pickle has been soaked with a solution of vinegar and salt. (ions are from the acid and Na+ and Cl-) The ions are able to carry the current. What color do you think the light emitted will be? Why would it be that color? You tube-electrocuting a pickle
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Strong acids produce a strong electric current = strong electrolyte
Strengths of Acids Acids that completely ionize (dissociate) are called strong acids. Strong acids produce a strong electric current = strong electrolyte HCl(aq) +H2O(l) H3O+(aq) + Cl-(aq) (notice there is a one way arrow meaning it completely ionizes and does not reform HCl)
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Strengths of Acids Weak acids partially ionize in solutions = weak electrolyte Produce fewer ions and cannot conduct electricity as efficiently as strong acids HC2H3O2(aq) +H2O(l) H3O+(aq) + C2H3O2-(aq) (notice there is a two way arrow meaning it partially ionizes and does reform HC2H3O2)
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Six Strong Acids Hydrochloric acid: HCl Hydrobromic acid: HBr
Hydroiodic acid: HI Sulfuric acid: H2SO4 Nitric acid: HNO3 Perchloric acid: HClO4 These acids completely dissociate in water.
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Eight Strong Bases Lithium hydroxide: LiOH Sodium hydroxide: NaOH
Potassium hydroxide: KOH Rubidium hydroxide: RbOH Cesium hydroxide: CsOH Calcium hydroxide: Ca(OH)2 Strontium hydroxide: Sr(OH)2 Barium hydroxide: Ba(OH)2 These bases completely dissociate in water.
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Acid/Base Strength vs. Concentration
Do not get acid/base strength confused with concentration. Acid/base strength is based on the ability to dissociate. Concentration is based on how much is dissolved in solution. You can have a strong dilute acid – the acid completely dissociates, but there is not much acid dissolved in solution
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Acid Ionization Constant
Acid ionization constant (Ka) is the value of the equilibrium constant expression(Keq) for the ionization of a weak acid. Large Ka strong acid (much greater than 1) Small Ka weak acid (much less than 1)
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Base Ionization Constant
The base ionization constant (Kb) is the value of the equilibrium constant expression (Keq) for the ionization of a base Large Kb strong base (much greater than 1) Small Kb weak base (much less than 1)
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Write the ionization equation and acid ionization constant (Ka) expressions for the acid HF
If you calculate Ka, it will be a weak acid so it will have a double arrow. Add it to water. HF(aq) + H2O(l) H3O+(aq) + F- (aq) (A) (B) (CA) (CB) Keq = Ka = [H3O+] [F -] [HF] Leave out liquids and solids in Keq But keep products over reactants
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Write the ionization equation and base ionization constant (Kb) expressions for the base NH3
If you calculate Kb, it will be a weak base so it will have a double arrow. Add it to water. NH3(aq) + H2O(l) NH4+ (aq) + OH- (aq) (B) (A) (CA) (CB) Keq = Kb = [NH4 +] [OH-] [NH3] Leave out liquids and solids in Keq But keep products over reactants
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