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NOTES: 2.2 – Properties of Water
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Water Overview… • Water is perhaps the most important compound in living organisms • Because so many substances can dissolve in water: molecules and ions are free to move and collide with one another in the reactions of life; water serves as a means of material transportation (i.e. blood, plant sap)
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Water Overview… Living cells are 70%-95% water
Water covers approx. ¾ of earth. In nature, water naturally exists in all 3 states of matter: solid, liquid and gas
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Water is a POLAR molecule
• the bonds that hold the hydrogen and oxygen atoms together are POLAR COVALENT BONDS… so, a water molecule has a positive end and a negative end
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Water is POLAR… • POLAR WATER MOLECULES attract one another, as well as ions and other polar molecules
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Water Molecules… • The polarity of water molecules results in HYDROGEN BONDING • a HYDROGEN BOND is the attraction of opposite charges between hydrogen and oxygen • How many hydrogen bonds can a single water molecule make with neighboring water molecules?
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Properties of Water (as a result of polarity and H-bonding):
► COHESION: molecules are held together by H bonds • contributes to upward movement of water in plants from roots to leaves
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Tension– Cohesion Model
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Properties of Water ► ADHESION: water sticks to other surfaces (by polarity or H bonds)… …can counteract gravity in plant vessels
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► SURFACE TENSION: measure of how difficult it is to stretch the surface of a liquid
-water has greater surface tension than most liquids because at the air/water interface the surface water molecules are H-bonded to each other and to the water molecules below -causes water to “bead” -creates a “skin” on the surface
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► HIGH SPECIFIC HEAT (resists changes in temp)
• Specific Heat: amt. of heat that must be absorbed or lost for 1 gram of a substance to change its temp by 1°C • Water’s high specific heat means that it resists temp. changes when it absorbs or releases heat *Heat is absorbed to break H-bonds; and given off when they form
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Compounds that are HYDROPHILIC (“water loving”), are soluble in water:
ionic compounds: charged regions of polar water molecules have an electrical attraction to charged ions polar compounds: charged regions of polar water molecules are attracted to oppositely charged regions of other polar molecules
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Compounds that are HYDROPHOBIC (“water fearing”) and are insoluble in water:
Nonpolar compounds: symmetric distribution in charge, or composed of nonpolar bonds
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► EVAPORATIVE COOLING: after high temp
► EVAPORATIVE COOLING: after high temp. molecules have evaporated, the remaining liquid is cooler (ex: sweating) -stabilizes temp. in aquatic ecosystems -protects organisms from overheating *(as 1 g of water evaporates from our skin, 539 g of body cools by 1°C)
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The air in the shower stall is at the same temperature as the air outside, but there's less water vapor outside to condense on the skin.
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HEAT OF VAPORIZATION (WHILE CHANGING STATE)
EVAPORATIVE COOLING HEAT OF VAPORIZATION (WHILE CHANGING STATE) SPECIFIC HEAT (WHILE WATER IS HEATING)
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► WATER EXPANDS WHEN IT FREEZES
• because of H-bonding, water is less dense as a solid than it is as a liquid...ice floats! • since ice is less dense, it forms on the surface at first • as water freezes, it releases heat to the water below and insulates it! • Oceans and lakes don’t freeze solid!!
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► WATER IS THE SOLVENT OF LIFE
cell ► WATER IS THE SOLVENT OF LIFE • due to its polarity, water is a versatile solvent
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Water forms Solutions All the components of a solution are evenly distributed throughout the solution. In a saltwater solution, table salt is the solute—the substance that is dissolved. Water is the solvent—the substance in which the solute dissolves.
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Acids, Bases, and pH Water molecules sometimes split apart to form hydrogen ions and hydroxide ions. This reaction can be summarized by a chemical equation in which double arrows are used to show that the reaction can occur in either direction.
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pH Scale Chemists devised a measurement system called the pH scale to indicate the concentration of H+ ions in solution. The pH scale ranges from 0 to 14. At a pH of 7, the concentration of H+ ions and OH– ions is equal. Pure water has a pH of 7. Acids have a pH less than 7. Bases have a pH greater than 7.
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