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Intermolecular Forces
Investigating the forces of attraction between molecules, and how they compare to ions and metals
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Vocab ____________: the forces of attraction between molecules
________: equal but opposite charges separated by a short distance ____________: the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule _____________: The intermolecular attraction resulting from the constant motion of electrons and the creation of instantaneous dipoles Intermolecular forces. Dipole. Hydrogen bonding. London dispersion forces.
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Boiling To understand the relative strength of intermolecular forces we must first understand how a ______ changes to a _____ If you increase the _________ of a liquid it will reach a point where it begins to boil The temperature of a substance is really just a measure of how ________ particles are moving Liquid. Gas. Temperature. Fast.
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Boiling Continued In a liquid the particles are moving slow enough that their attractions cause them to _______ together. But they are still able to ______ past each other. In a gas the particles are moving so fast that the attractions between ________ is no longer able to cause them to stick together This means boiling is the point where the particles are moving so fast they can overcome the _________ holding them close together in liquids Watch it in action Clump. Flow. Particles. Attraction.
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Relative Strength The _____ is a good measure of the force of attraction between particles. IMF vary in strength, but are generally ______ than the bonds joining atoms in molecule, ions in compounds, or metal atoms in solid metals Section 6.5: Intermolecular Forces Boiling point. Weaker.
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Intermolecular Forces
In this section we will focus only on the attractive forces between separate _________ There are a variety of intermolecular forces, and each of them varies in _________ Molecules. Strength.
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Dipole-Dipole Forces The ________ IMF exist between polar molecules
Polar molecules act as _______ because of their uneven charge distribution The direction of a dipole is from the _____ pole to the _____ pole. Used a crossed arrow to indicate a dipole. Strongest. Dipoles. Positive. Negative.
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Dipoles Continued The negative region in one polar molecule attracts the _______ region in an adjacent polar molecule The forces of attraction between polar molecules are known as ______-______ forces Effect can be seen by comparing boiling points of polar and __________ molecules
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Molecular Polarity The polarity of molecules with more than one bond depends on not just polarity of individual bonds, but also on __________ of each bond This means we must always consider _________ when determining molecular polarity
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Molecular Polarity Examples
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Hydrogen Bonding Some hydrogen containing compounds have unusually ____ boiling points (HF, H2O, NH3) This is caused by a strong type of dipole-dipole force called _________________ Only compounds made from ____, _____, and _____ with H can make hydrogen bonds High. Hydrogen bonding. Fluorine, oxygen, and nitrogen.
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Hydrogen Bonding Continued
Hydrogen bonds form when the electronegative atoms form a highly _______ bond with H The small and positively charged H atom forms a very strong attraction with _________ electrons on an adjacent molecule Polar. A lone pair of
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Strength Comparison of Hydrogen Bonding
Boiling point of phosphine (PH3)_______ Boiling point of ammonia (NH3)________ BP H2S ________ BP H2O ________
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Induced Dipoles A polar molecule can _______ a dipole in a nonpolar molecule by temporarily attracting its _________ This creates a temporary dipole with the side nearest the attracted electrons becoming partially _________ charged This is a _______ attraction than dipole-dipole attractions Induce. Electrons. Negatively. Weaker.
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London Dispersion Forces
The random movement of electrons creates uneven distribution of _________ At any moment there could be a short-lived and weak ______ created These are the only forces between _______ gas atoms and ___________ molecules The ________ of all attractive forces Electrons. Dipole. Noble. Nonpolar. Weakest.
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