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Published bySzebasztián Bakos Modified over 6 years ago
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Why??? As you’ve already seen… Chemical reactions occur around us everyday--- so many in fact that looking at them all individually would be REALLY overwhelming! So instead we name them based what happens!
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Classification of Chemical Reactions
Chemical reactions can be classified in one of two ways: Based on atoms moving (rearrangement) Based on how energy/ heat is transferred Vs.
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Classifying based on atoms moving
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where A and B may be either elements or compounds.
1) Synthesis Reaction Boy + Girl = Couple This is a reaction in which two or more elements or compounds combine to form a single product. This type of reaction follows the general equation A + B AB where A and B may be either elements or compounds. +
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Example: Synthesis Burning Magnesium
2Mg + O2 2MgO
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Decomposition Reaction
The couple breaks up! In this type of reaction a single reactant, a compound, breaks into two or more parts. Often these are the most difficult to predict. Here is the general equation: ABA + B where A and B may be either elements or compounds. +
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Example: Decomposition Hydrogen Peroxide
2H2O2 2H2O +O2
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Single Replacement Reaction
+ + Single Replacement Reaction In this type of reaction, a more reactive element replaces a less reactive element in a compound. For the metals, you will need to use an activity series (like the one in your notes)– the higher the element is the more REACTIVE it is. The general equation: A + BC AC + B where A is a metal. A + BC C + BA Like one girl switching dance partners!
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Example: Single Replacement Magnesium and Carbon Dioxide
2Mg + CO2 2MgO + C
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Double Replacement Reaction
+ + Double Replacement Reaction In this type of reaction, two compounds react to form two new compounds. The formation of a molecular compound such as water, the formation of a gas, or the formation of a precipitate usually drives these reactions. Here’s the general equation: AB + CD AD + CB Note: “Metals” replace “metals” and non-metals replace non-metals Like 2 pairs of dancers changing partners
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Example: Double Replacement Potassium Iodide and Lead (II) Nitrate
2KI(aq) + Pb(NO3)2(aq) 2KNO3(aq) + PbI2(s)
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CxHy + O2(g) CO2(g) + H2O(l) or (g)
Combustion Reaction In this type of reaction, a hydrocarbon is burned in the presence of oxygen gas to form carbon dioxide and water. Here is the general equation in the presence of plenty of oxygen: CxHy + O2(g) CO2(g) + H2O(l) or (g) Note: If combustion is inefficient (insufficient oxygen) then carbon monoxide is formed!
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Example: Combustion Burning Methane (Natural Gas)
CH4 + 2O2 CO2 + 2H2O
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Neutralization Reactions
Unfortunately we cannot forget about neutralization reactions (a.k.a. acid-base reactions)! In this type of reaction, an acid and a base react to form a salt and water. The general equation for this type of reaction is: HX + MOH MX +H2O Where M is a metal ion and X is a non-metal ion
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Classifying based on energy transfer
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Endothermic vs. Exothermic
Reactions are classified by looking at whether energy is required or released during a chemical reaction: EXOTHERMIC (exo= outside)- energy is released during a chemical reaction (i.e. is a product), given off as heat ENDOTHERMIC (endo= inside)- energy is required during a chemical reaction (i.e. is a reactant), and heat is absorbed
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Example of an Exothermic Reaction: Decomposition of H2O2
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Example of an Endothermic Reaction: The “Green” Cold pack— Ammonium Nitrate in Water
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Six Questions to find the type of Chemical Reaction
Follow this series of questions. When you can answer "yes" to a question, then stop! 1) Does your reaction have oxygen as one of it's reactants and carbon dioxide and water as products? If yes, then it's a combustion reaction 2) Does your reaction have two (or more) chemicals combining to form one chemical? If yes, then it's a synthesis reaction 3) Does your reaction have one large molecule falling apart to make several small ones? If yes, then it's a decomposition reaction
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Six Questions to find the type of Chemical Reaction cont.
4) Does your reaction have any molecules that contain only one element? If yes, then it's a single displacement reaction 5) Does your reaction have water as one of the products? If yes, then it's an acid-base reaction 6) If you haven't answered "yes" to any of the questions above, then you've got a double displacement reaction
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Practice Problems Fe2O3 C18H38 +O2 Al + NiBr2 Li + N2
Cl2 + NiBr2 AgNO3 + Na2CrO4 HCl + Mg(OH)2
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Fe2O3 Skeleton Equation: Fe2O3 Fe + O Balanced Equation:
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Al + NiBr2 Skeleton Equation: Al + NiBr2 Ni + AlBr3
Balanced Equation: 2Al + 3NiBr2 3Ni + 2AlBr3
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Cl2 + NiBr2 Skeleton Equation: Cl2 + NiBr2 Br2 + NiCl2
Balanced Equation:
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HCl + Mg(OH)2 Skeleton Equation: HCl + Mg(OH)2 MgCl2 + H2O
Balanced Equation: 2HCl + Mg(OH)2 MgCl2 + 2H2O
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C18H38 +O2 Skeleton Equation: C18H38 +O2 CO2 + H2O
Balanced Equation: 2C18H O2 36CO2 + 38H2O
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Li + N2 Skeleton Equation: Li + N2 Li3N Balanced Equation:
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AgNO3 + Na2CrO4 Skeleton Equation: AgNO3 + Na2CrO4 NaNO3 + Ag2CrO4
Balanced Equation: 2AgNO3 + Na2CrO4 2NaNO3 + Ag2CrO4
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