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II. Graham’s Law of Diffusion & Effusion
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A. Kinetic Energy The average kinetic energy of molecules is directly proportional to the absolute temperature
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A. Kinetic Energy KE = ½ mv2
KE = kinetic energy m = mass v = velocity **At any given temperature, the molecules of ALL gases have the same average kinetic energy
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B. Diffusion vs. Effusion
Diffusion – tendency of molecules to move towards area of lower concentration until the concentration is uniform throughout
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B. Diffusion vs. Effusion
Effusion – the movement of gas particles through a small hole
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B. Diffusion vs. Effusion
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C. Comparison of Molecules
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C. Comparison of Molecules
Image two gas samples, one of He (4 g/mol) and one of Ne (20 g/mol). If both have a kinetic energy of 2 J, what speed are both moving at? Use KE = ½ mv2 He: 2 J = ½ (4 g) x v2 Ne: 2 J = ½ (20 g) x v2
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HEAVIER GAS PARTICLES MOVE (DIFFUSE & EFFUSE) SLOWER
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D. Graham’s Law Recall: If 2 gases (A and B) are at the same temperature, the molecules have the same average kinetic energy. KEA = KEB ½ mAvA2 = ½ mBvB
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D. Graham’s Law of Diffusion
Example: Mixture of He (4 g/mol) and Ne (20.2 g/mol)
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Find the ratio of diffusion rates of O2 and N2
Graham’s Law Example Find the ratio of diffusion rates of O2 and N2
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