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Dissolving Part II: Dissociating / Ionizing
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OUTCOME QUESTION(S): C11-4-03 DISSOVING PROCESS Vocabulary & Concepts
Describe and give examples of various types of solutions. Include: suspension, emulsion, colloid, alloy, solute, solvent, soluble, insoluble, miscible, immiscible Describe the chemical structure of compounds in terms of electronegativity and polarity of bonds. Include: polar and non-polar Explain the solution process of simple ionic and covalent compounds, using visual, particulate representation and chemical equations Include: hydration, heat of solution, dissolve, dissociate Vocabulary & Concepts Ionize Electrolyte Non-electrolyte
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**The general dissolving rule is like dissolves like.**
Dissociating: when ionic compounds separate into ions during dissolving. Cl - Na + Think of dissociating as “dissolving part 2” Ionizing: when very polar covalent compounds separate into ions during dissolving. δ- Cl Most polar compounds DO NOT ionize – ionization typically releases hydrogen ions δ+ H
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All ionic bonds will dissociate when dissolving
Case 1: Polar solvent with Ionic solute H O δ- δ+ DISSOCIATE H O δ- δ+ H O δ- δ+ √ H O δ- δ+ - Cl Cl - Na + + Na All ionic bonds will dissociate when dissolving Attractive Force
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Ionizing typically occurs with acids
Case 2: Polar solvent with very Polar solute H O δ- δ+ IONIZE H O δ- δ+ H O δ- δ+ √ H O δ- δ+ δ- Cl Cl δ- H δ+ δ+ H Attractive Force Ionizing typically occurs with acids
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X Case 3: Polar solvent with Polar solute IONIZE
δ- δ+ H O δ- δ+ H O δ- δ+ IONIZE X H O δ- δ+ H O C δ- δ+ H O C δ- δ+ Polar enough to dissolve as whole molecules, NOT polar enough to ionize Attractive Force
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Ions in solution can conduct an electric current
Electrolyte: Ions in solution can conduct an electric current If it dissociates /ionizes it creates electrolytes *The more soluble a solute is, the more electrolytes produced, the stronger the current* Non-polar and weakly polar compounds are non-electrolytes Identifying very polar compounds that ionize (electrolytes): Molecular compounds with isolated H atoms at the beginning or end of formula separate into ions CH3COOH HNO HF
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ions conduct electricity
Sugar is polar enough to dissolve, NOT polar enough to ionize Electrolytes ions conduct electricity
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The dissociation or ionization of a substance in water can be shown using chemical equations.
dissociate NaCl(s) Na+(aq) + Cl–(aq) electrolytes dissolve C11H22O11(s) C11H22O11(aq) non-electrolyte ionize CH3COOH CH3COO-(aq) + H+(aq) electrolytes Will it dissolve (ionic or polar)? - use the (aq) notation to show dissolving 2. Will it dissociate (ionic or “special” H)? 3. Write the balanced equation - ion charges MUST BE included!
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Al+3 SO4-2 Al2(SO4)3 (s) 2 Al+3 + SO4-2 (aq) 3 (aq)
Write the equation for aluminum sulphate in water. metal polyatomic ion Al SO4-2 Al2(SO4)3 (s) 2 Al SO4-2 (aq) 3 (aq) Notice that the ions used to build the compound are the same that it dissociates into Will it dissolve (ionic or polar)? - use the (aq) notation to show dissolving 2. Will it dissociate (ionic or “special” H)? 3. Write the balanced equation - ion charges MUST BE included!
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CAN YOU / HAVE YOU? C11-4-03 DISSOVING PROCESS Vocabulary & Concepts
Describe and give examples of various types of solutions. Include: suspension, emulsion, colloid, alloy, solute, solvent, soluble, insoluble, miscible, immiscible Describe the chemical structure of compounds in terms of electronegativity and polarity of bonds. Include: polar and non-polar Explain the solution process of simple ionic and covalent compounds, using visual, particulate representation and chemical equations Include: hydration, heat of solution, dissolve, dissociate Vocabulary & Concepts Ionize Electrolyte Non-electrolyte
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