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Liming and Liming Materials
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pH value defines relative acidity or basicity
9.0 8.0 Basicity Most Productive Soils pH value defines relative acidity or basicity 7.0 Neutrality 6.0 Acidity 5.0 pH = - log[H+] 4.0
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What Causes Soil Acidity?
Rainfall leaches basic elements (Ca++, Mg++, Na+, K+) Acidic parent material granite more acidic than shale or sandstone Organic Matter OM decay produce H+ Harvest of high yielding crops most significant role
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- - - - clay - - - - - - - Soil Acidity H+ Al3+ H+ H+ H+ H+ Ca2+
(Cation Exchange) (Soil Solution) H+ Ca2+ pH = - log[H+]
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How Lime Reduces Soil Acidity
A Ca2+ ion from the lime replaces two H+ ions on the cation exchange complex The H+ ions combine with OH- to form water Soil pH increases because the acidity source (H+) has been reduced
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Neutralizing Acidity with Lime
CaCO3 + H2O Ca HCO OH- Displaces Al & H from Clay Breaks down to carbon dioxide + water Combines with H+ released from the clay or from Al-OH to form water
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- - - - - - - - - - - - - - - - - - - - - - How Lime Works clay clay
CaCO3 (Lime) Ca HCO OH- - - - - - - clay Ca2+ - - - - - + H2O CO2 (Carbon Dioxide) (Water)
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- - - - - - - - - - - - - - - - - - - - - - How Lime Works clay clay
Al+++ - - clay - - - - - CaCO3 (Lime) Ca HCO OH- - - - - H2O - - clay Ca2+ - - - - - Al H2O --> Al(OH)2+ + 2H+ Al(OH) H2O CO2 (Carbon Dioxide) (Water)
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Lime Materials: Effectiveness is Determined: Particle Size
Neutralizing Power
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10 mesh 1/8” 3/16” 20 mesh 1/4” 100 mesh 1/2” 200 mesh 3/4”
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FINENESS PPI
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AgLime Mesh Size Specifications: Virginia
Ground Limestone Mesh Guar. to Pass % % % Pulverized Lime % %
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Neutralizing Power or Calcium Carbonate Equivalency (CCE)
CaCO3 set to 100. All other materials compared to it.
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Neutralizing Value (CCE) of Pure Compounds
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Lime Neutralizing Power
Purity: minimum calcium carbonate equivalency (CCE) of 85%
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Properties of various lime materials
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Which Lime Should I Use? Dolomitic Calcitic Hydrated Burned Suspension
Pelleted Ag Marl
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Liming When is the best time to apply?
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Apply Lime Well Ahead of Planting
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5.0 6.0 7.0 Sandy Loam Silt Loam 1.5 tons 2.5 tons pH
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