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Gay-Lussac’s and Combined Gas Laws
Unit: Gas Laws Gay-Lussac’s and Combined Gas Laws
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After today you will be able to…
Explain the effect on gas properties using Gay-Lussac’s Law and the Combined Gas Law Calculate an unknown pressure, temperature, or volume by solving algebraically
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Gay-Lussac’s Law: Pressure and Temperature
Joseph Gay-Lussac discovered the relationship between temperature and pressure. His name is on the gas law that describes this relationship.
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“For a given volume of a gas, as the temperature of an enclosed gas increases, the pressure of a gas is directly proportional.”
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Gay-Lussac’s Law: Pressure and Temperature
We can simplify this relationship by the formula: Where, P1, P2 = pressure in any unit (atm, kPa, or mmHg), BUT they must match! T1, T2 = temperature is always in Kelvin! (Recall, just add °C) P1 P2 T1 T2 =
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Gay-Lussac’s Law: Example
A gas has a pressure of 103kPa at 25°C. What will the pressure be when the temperature reaches 928°C? P1= T1= P2= T2= 103kPa P1 P2 T1 T2 = 25°C +273= 298K ? 928°C+273= 1201K (103kPa) (P2) = (298K) (1201K) P2 = 420kPa
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The Combined Gas Law The combined gas law is a single expression that combines Boyle’s, Charles’s, and Gay-Lussac’s Laws. This gas law describes the relationship between temperature, pressure, and volume of a gas. It allows you to do calculations where only the amount of gas is constant. RB + JC + JG-L = BFFs!
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P1V1 P2V2 T1 T2 = The Combined Gas Law
Helpful hint: You are able to get which law you need by covering the variable that is not mentioned in the problem! There is no need to memorize 4 individual laws, just memorize the Combined Gas Law and you can derive all of the others! If there is no mention of pressure in the problem, cover P up and you are left with the relationship between T and V. (aka Charles’s Law!) If there is no mention of volume in the problem, cover V up and you are left with the relationship between T and P. (aka Gay-Lussac’s Law!) For example, if there is no mention of temperature in the problem, cover T up and you are left with the relationship between P and V. (aka Boyle’s Law!) P1V1 P2V2 T T2 =
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The Combined Gas Law P1 V1 P2 V2 = T1 T2 P2 467mmHg = P1= V1= T1= P2=
A gas occupies 3.78L at 529mmHg and 17.2°C. At what pressure would the volume of the gas be 4.54L if the temperature is increased to 34.8°C? P1= V1= T1= P2= V2= T2= P1 V1 P2 V2 T T2 = 529mmHg 3.78L 17.2°C + 273= 290.2K (529mmHg) (3.78L) (P2) (4.54L) ? = (290.2K) (307.8K) 4.54L 467mmHg 34.8°C + 273= 307.8K P2 =
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