1. ENERGY
I am teaching Engineering Thermodynamics using the textbook by Cengel and Boles.
A few figures in the slides are taken from that book, and most others are found online.
Similar figures can be found in many places.
I went through these slides in one 90-minute lecture.
Zhigang Suo, Harvard University

2. System Experimental setup A fixed number of H2O molecules Cylinder
Frictionless, perfectly sealed piston
Weights
Fire
System
A system can be any part of the world.
Here the system is a fixed number of H2O molecules in the cylinder.
The rest of the world is called the surroundings of the system.
The system interacts with its surroundings
Weights transfer energy to the system by work.
Fire transfers energy to the system by heat.
Closed system
The system exchange energy with its surroundings.
The system does not exchange matter with its surroundings.
Isolated system
An isolated system does not interact with the rest of the world.
No exchange of matter. Seal the cylinder.
No exchange of energy. Jam the piston. Insulate the cylinder.
Do whatever necessary to prevent the rest of the world from affecting the system.

3. Energy
The world has many parts: stars, planets, animals, molecules, electrons, protons...
The parts move relative to one another, and interact with one another.
The motion and interaction carry energy.
Energy is a fundamental concept.
We don’t know how to define energy in more fundamental concepts.
But we do know ways to measure and calculate energy.
That is all that matters.

4. Potential energy m When a mass m is lifted by a distance z,
The energy increases by
mgz.
We call this energy the potential energy.
State 2 z m
state 1

5. Kinetic energy velocity v stationary m m state 1 state 2
From the stationary state to a state of velocity v, the energy increases by
We call this energy the kinetic energy.

6. Zero-sum game state 1 velocity = 0 height = 0 h state 2 velocity = v
state state 1

7. Newton’s second law z mg

8. Vocabulary Forms of energy (kinetic energy and potential energy)
Conversion of energy from one form to another form.
Transfer of energy from one part of the system to another part.
Conservation of energy. When kinetic energy and potential energy convert to each other, their sum is fixed. Really?

9. Elastic energy Isolated system
Gradually add weights from different heights to pull the spring.
When the length of the spring is x, the amount of weights to maintain the length of the spring is F(x).
When the length increases by dx the potential energy of the weights reduces by F(x)dx.
The total reduction of the potential energy of the weights is
The same amount of energy is added to the spring as elastic energy.
The spring is a lattice of atoms. The elastic energy is stored in the stretched atom bonds.
How do I know? Gradually remove the weights to place them back to the original heights.
(Isolated system) = weights + spring.
(energy of the system) = (potential energy of the weights) + (elastic energy of the spring) = constant
Isolated system

10. Force-length curve Ideal spring Force, F Force, F loading loading
unloading
Elongation, x
Elongation, x

11. Force-length curve dissipative spring Force, F energy dissipated
by the spring
loading
unloading
Elongation, x

12. Force-length curve dissipative spring Force, F energy dissipated
(isolated system) = weights + spring + (insulated room)
(potential energy of the weights) + (elastic energy of the spring) + (internal energy of the room) = constant
Force, F
energy dissipated
by the spring
loading
unloading
Elongation, x

13. A game-changing idea The principle of the conservation of energy A new zero-sum game
An isolated system has a fixed amount of energy.
What if energy of all known forms is not conserved?
Discover another form of energy to make energy conserve.
But what qualifies as a new form of energy?
Anything that can convert to a known form of energy.
Sounds like a self-fulfilling prophesy. It is.
My view on the principle of the conservation of energy follows, I believe, Feynman.
Read his tale of “Dennis the Menace”.
The Feynman’s Lectures ought to be required reading for all engineers.

14. Joule’s discovery
decreases

15. Internal Energy Isolated system
(isolated system) = fluid + paddle + weight
(internal energy) + (kinetic energy) + (potential energy) = constant

16. Internal energy and molecular motion
Even when a tank of water is stationary at a macroscopic scale,
water molecules undergo rapid and ceaseless motion.

18. Electrical energy
(isolated system) = battery + bulb + (insulated room)
(chemical energy of the battery) + (internal energy of the room) = constant
Energy per unit time (power) going out the battery = VI
Isolated system
bulb
conductor of
negligible resistance
current I
voltage V
battery

19. Convert chemical energy to electrical energy
lithium-ion battery
Lithium-ion
wire
electrolyte
electrode
electrode
Electrodes host lithium atoms.
(lithium atom) = (lithium ion) + (electron)
Electrolyte conducts lithium ions.
Wire conducts electrons.

20. Surface energy of liquid
Molecules on surface have different energy from those in the interior.
When the area of surface increases, more molecules come to the surface.
The extra energy of the surface is proportional to the area of the surface:
ss is the surface energy (per unit area).

21. Convert energy from one form to another
kinetic
potential
light
electrical
chemical
nuclear
thermal
turbine
falling object
solar
sail
motor
explosion
atomic bomb
steam engine
rising object
seesaw
electric
pump
balloon
tribo-
luminescence
light bulb
chemo-
fire
generator
hydro-electric
photo-electricity
circuit
discharge
battery
nuclear power station
thermo-
electricity
photo-
synthesis
charge
chemical reaction
nuclear reaction
friction
radiator
heat exchanger

22. Systems interact with the rest of the world in various ways
Exchange matter
Exchange energy
by work
by heat
Open system
yes
Isolated system no
Closed system
Thermal system
Adiabatic system

23. From isolated system to closed system
(Isolated system) = (weights) + (ideal spring)
(closed system) =( ideal spring)
Force acting on the spring by the weights: F(x).
work done to the spring by the weights: F(x)dx.
Change in the elastic energy of the spring: dU = F(x)dx.
Isolated system
closed system

24. Electrical Work work per unit time (power) going out the battery = VI
closed system
bulb
conductor of
negligible resistance
current I
voltage V
battery

25. Adiabatic work changes internal energy
Variations of Joule’s experiment

26. Transfer energy to a closed system in two ways—heat and work
System = water
thermal contact adiabatic contact
So far as water is concerned, the two ways of adding energy give the same result.
Internal energy is a property of the closed system.
Increase the internal energy of the closed system.
Work and heat are not properties of the closed system.
Thermal contact: transfer energy by heat.
Adiabatic contact: transfer energy by work.

27. THE FIRST LAW OF THERMODYNAMICS
For all adiabatic processes between two states of a closed system, the net work done is the same regardless of the nature of the closed system and the details of the process.
Determine the change in internal energy by adiabatic process, DU = W.
For a closed system, in general DU is not equal to W.
The difference defines heat, DU = W + Q.

28. Mechanisms of transferring energy by heat
Conduction
Convection
Radiation

29. Yang, Stabler, Journal of Electronic Materials. 38, 1245 (2009)

30. What you need to know about energy, The National Academies.

31. 31

32. Summary Forms of energy. Convert energy from one form to another.
Energy is additive.
Transfer energy from one place to another.
The energy of an isolated system is conserved.
The internal energy of a closed system changes due to heat and work.