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Objectives/Goals for Today
Discuss logistics of homework Quiz over Chapter 1 Chapter two notes Section 2.1 Section 2.2 Break Section 2.3 Section 2.4 Section 2.5 Section 2.6
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Chapter Two Atoms & The Periodic Table
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Section 2.1 Atoms First
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Atoms Atoms are the smallest quantities of matter that still retain the property of that matter
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A brief history Democritus was the first to develop this idea of an atom in the 5th century John Dalton was the first to formalize the idea of an atom with Dalton’s atomic theory Known as the “father of atomic theory” The word “atom” comes from the Greek word “atomos” meaning “uncuttable.”
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Dalton’s Atomic Theory
All matter is made up of atoms Atoms are indivisible Atoms of the same element are identical Atoms of one element are different than atoms of another element Atoms come together to form compounds
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Dalton’s Law of Multiple Proportions
If two elements can combine to create multiple compounds, then the ratios of the masses of the second element which combine with a fixed mass of the first element will be ratios of small whole numbers CO CO2 100 g of C g of C 133 g of O g of O
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Section 2.2 Subatomic Particles & Atomic Structure
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Discovery of the Electron
Late 1800s; discovered by J.J. Thomson
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Discovery of the Electron
Thomson performed many experiments with variable electric fields and measured degree of reflection Charge-to-mass ratio 1.76 x 108 C/g (C stands for coulomb)
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Charge of an Electron Early 1900s; discovered by Robert Millikan
Oil Drop Experiment
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Charge of an Electron Millikan used Thomson’s charge-to-mass ratio to determine the mass of an electron
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The Proton Atoms are neutral; need for a positive particle
Thomson believed in the plum pudding model
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The Proton Rutherford contested this with the Gold Foil Experiment
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The Proton & The Nucleus
Rutherford proposed all of the atom’s positive charge in the core of atom called the nucleus
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Proton vs. Electrons Protons: in the nucleus
Provide same charge as electrons, only opposite sign Provide the mass of the atom (nearly 2000 times more massive than electrons) Electrons: outside the nucleus Provide the volume of atom
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The Neutron Discovered by James Chadwick in 1932
Practically same mass as proton No charge
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Break Be back in 5!
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Section 2.3 Atomic Number, Mass Number and Isotopes
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Element Symbols
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Isotopes Not all atoms of a given element are identical
Most elements have 2 or more isotopes (atoms with same # of protons, different # of neutrons)
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Isotopes Isotopes behave like each other Named after their mass number
Ex: U-235 (“Uranium two thirty five”)
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Ions Atoms with charges (different # of electrons)
Positive ions called cations Negative ions called anions
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Practice List the number of protons, neutrons, and electrons in the following elements: Carbon-14 Iodine-128 An atom has a mass number of 114 and 66 neutrons. Write the isotope notation for this atom.
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Section 2.4 Average Atomic Mass
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Average Atomic Mass Mass of an atom in atomic mass units (a.m.u)
Based off of 1/12 of a carbon atom Most elements are mix of isotopes in nature Average Atomic Mass is reported
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Practice The atomic masses of two stable isotopes of copper, copper-63 and copper 65, are and amu, respectively. If copper-63 is 69.17% and copper-65 is 30.83%, what is the average atomic mass of copper?
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Break! Be back in 5!
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Section 2.5 The Periodic Table
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The Periodic Table Mostly metals (left of stair step)
Good conductors of heat/electricity Non metals (right of stair step) Poor conductors of heat/electricity Metalloids/Semi-metals (on stair step) Properties of both metal and nonmetal B, Si, Ge, As, Sb, Te, Po, At
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The Periodic Table Groups: vertical columns Periods: horizontal rows
Elements in the same group share similar chemical properties 18 groups Periods: horizontal rows Elements transition from metal to nonmetal across a period
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The Periodic Table
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Section 2.6 The Mole and Molar Mass
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The Mole A unit of quantity (how much)
Mole = mol 1 mole = x 1023 “particles” “particles” can be atoms, molecules, or formula units
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Molar Mass Molar Mass = the mass of ONE MOLE of a substance g/mol
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Molar Mass 1 mole of water = 18.02 grams
1 mole sodium chloride = g 1 mole helium gas = g
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Molar Mass Molar mass is found by Listing elements in compound
Determining their mass found on periodic table Multiplying by how many atoms there are Adding these values Ex: H2SO4
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Conversions How many molecules of magnesium chloride (MgCl2) are there in grams of magnesium chloride? How many chlorine atoms are there in the same mass of magnesium chloride?
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A helpful guide
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Group Quiz 1)Describe the contributions of Thomson, Millikan, Rutherford, & Chadwick (include experiments where applicable) 2)Write the appropriate symbol for the following: Z=28, A=64 3)How many protons, neutrons, & electrons in 4)Rb-85(72.17%) is If the average atomic mass of Rb is , what is the atomic mass of Rb-87(27.83%). 5)Name 2 elements from each of the groups of the periodic table discussed today 6)How many grams is 5.30 x 1023 molecules of K2O? +3
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