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Ch. 7/8 Notes Day 1
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Objectives SWBAT explain how elements and atoms become ions when forming bonds SWBAT to identify trends in the periodic table (atomic radius, ionization energy, electronegativity) SWBAT explain why some bonds might form over others
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Quick Review Electron Configuration – how electrons are arranged in energy levels and orbitals around a nucleus Energy Level – the location (“house”) that contains orbitals (“rooms”) where electrons “live.” Also called SHELLS The BIGGER the energy level, the BIGGER the house
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Think of it like this…. High Energy Low Energy 1st Energy Level
2nd Energy Level 3rd Energy Level 1st Energy Level Orbitals Orbital Orbitals
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Electron Configuration for Energy Levels
Energy Level (Shell) # of Electrons 1 2 8 3 18 4 32 5 50 6 72 Away from Nucleus
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How to construct electron configurations
Rules Start on the inside and work your way out COMPLETELY fill each shell as you work your way out Whatever is left over in the outer-most shell, is your number of VALENCE electrons
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Electron-Dot Diagrams
Write the chemical symbol for each element, then place the number of valence electrons around the symbol on 4 sides. Keep placing one dot on each side, until you have the number of valence electrons NOTE: you should not have more than 2 per side, for a total of 8.
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New Stuff
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Ions Ion – an atom that has a NET positive or NET negative charge Anion – an atom that has a NET negative charge Nonmetals will always become ANIONS Cation – an atom that has a NET positive charge Metals will always become CATIONS **GAINS one electron to fill the octet. Now has 10 e- total. Protons +9 Electrons -9 Charge F Protons +9 Electrons -10 Charge -1 F **LOSES two electron to empty the octet. Now has 18 e- total. Protons +20 Electrons -20 Charge Protons +20 Electrons -18 Charge +2 Ca Ca
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Practice… What’s the charge? Anion or Cation?
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Ch. 7/8 Notes Day 2
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Objectives Students will be able to use electronegativity relates to electron affinity, and how it relates to the strength of an ionic bond. Students will be able to explain and demonstrate naming and formula writing conventions for ionic bonds given elements, or formula names
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Review
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Atomic Radius Atomic Radius – the distance from the center of an atom (nucleus) to the outermost electron orbital Atomic Radius DECREASES Atomic Radius INCREASES
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Ionization Energy Ionization Energy – how easy it is to pull an electron out of an atom The LARGER the atomic radius, the lower the ionization energy. It’s easier to pull an electron out of a large atom than a small atom. Ionization Energy INCREASES Ionization Energy DENCREASES
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Electron Affinity Electron Affinity – how much an atom will attract additional electrons How “hungry” an atom is for more electrons. The opposite of ionization energy The smaller the atomic radius, the higher the electronegativity. Electron Affinity INCREASES Electron Affinity DECREASES
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New Stuff
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Electronegativity Trick: Move right to left first, then check up and down Electronegativity – how much an atom will attract additional electrons How “hungry” an atom is for more electrons. The opposite of ionization energy The smaller the atomic radius, the higher the electronegativity. Pauling Scale Rates electronegativity on a scale from 0.7 to 4.0. The bigger the difference in electronegativity, the stronger the bond Electronegativity INCREASES Electronegativity DENCREASES
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Ionic Bond Review Ionic Bond – The force of attraction that holds cations (+) and anions (-) together This force is caused by the TRANSFER of electrons from a cation to an anion. Na F
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Dot Bonding Review Na Cl Li O Li
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Writing Formulas Rules
Cation (+) ALWAYS comes first Usually a METAL Anion (-) ALWAYS comes second Usually a NonMetal If there is more than 1 of an atom in the formula, write it as a subscript Li O Li Li2O AlCl3
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Ch. 7/8 Notes Day 3
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Objectives Students will be able to check their Lewis Dot models of ionic bonding with a shortcut method of checking atomic charge and bond ratios
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Ionic Formula Shortcut
You MUST KNOW how to construct dot models. The shortcut is just a quick check… You DO NOT need to write a 1 in the formula. If the numbers are the same, they reduce to 1’s, and don’t write them. Mg +2 O -2 B +3 S -2 Mg +2 I -1 Mg2O2 B2S3 Mg1I2 MgO B2S3 MgI2
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Naming Ionic Bond Rules
The name of the CATION always comes FIRST Use the FULL NAME of the cation The name of the ANION always comes LAST Use the ROOT NAME of the anion, then add –IDE Anion Name Examples Fluorine -> Fluoride Iodine -> Iodide Sulfur -> Sulfide Nitrogen -> Nitride Phosphorous -> Phosphide
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Li3P NaCl BaS Fr2O Lithium Phosphide Sodium Chloride Barium Sulfide
Ionic Naming Practice Li3P NaCl BaS Fr2O Lithium Phosphide Sodium Chloride Barium Sulfide Francium Oxide
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Ionic Naming & Bonding Practice
Name of the Compound Write the Formula for the Compound NaBr CaO Li2S MgBr2 BeO2 NaCl Cs2Se Potassium Iodide Magnesium Oxide Aluminum Chloride Beryllium Phosphide Calcium Chloride Aluminum Oxide Ammonium Chloride
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Atomic Dating Activity Review
(Disregard. We are not doing this, this year.)
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Dating Data Symbol Electroneg. Radius (pm) H 2.20 53 B 2.04 87 Li 0.98
167 C 2.55 67 Be 1.57 112 N 3.04 56 Na 0.93 190 O 3.44 48 Mg 1.31 145 F 3.98 42 K 0.82 243 Si 1.00 111 Ca 194 P 2.19 98 Rb 265 S 2.58 88 Sr 0.95 219 Cl 3.18 79 Cs 0.79 298 As 2.18 114 Ba 0.80 253 Se 103 Fr 0.7 270 Br 2.06 94 Ra 278 I 2.68 115 Te 2.10 123 At 127
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Ch. 7/8 Notes Day 4
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Objectives SWBAT explain the difference between ionic bonds and covalent bonds SWBAT to correctly name and draw Dot- Bonds for the compounds created
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Polyatomic Ions Polyatomic Ions- naturally occurring combinations of elements that are “stuck” so tightly together that they act as a single atom Naming Rules: (-ide)- element off of the periodic table (-ite)- polyatomic ion (-ate)- polyatomic ion Examples BaS – Barium Sulfide BaSO3 – Barium Sulfite BaSO4 – Barium Sulfate
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Variable Charge Elements
Elements that can have more than 1 charge Typically Transition Metals (Groups 3-12) The charge is given by Roman Numerals Examples Lead (II) = Pb+2 Lead (IV) = Pb+4 Copper (I) = Cu+1 Copper (III) = Cu+3
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Ch. 7/8 Notes Day 5
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Objectives SWBAT explain the difference between ionic bonds and covalent bonds SWBAT to correctly name and draw Dot- Bonds for the compounds created
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Covalent Bonds Covalent Bond – a chemical bond where two or more atoms SHARE a pair of valence electrons Molecule – a neutral group (no charge) of atoms that are joined together by covalent bonds Lewis Structure – a model of boding between elements, usually represented by dots. A “Dot-Bond” Prefix – a Latin root that comes BEFORE the name of an atom that tells how many atoms are there
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Special Covalent Bonds
Diatomic Molecules – seven NONMETALS that ALWAYS stick to themselves Covalent naming rules DO NOT apply. Just name from periodic table. N2 - Nitrogen H2 - Hydrogen F2 - Fluorine O2 - Oxygen I2 - Iodine Cl2 - Chlorine Br2 - Bromine Never Have Fear Of Ice Cold Beer
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F Cl Cl S Cl Covalent Bonds Group 16 Elements
Usually form 2 Bonds, can form up to 6 Bonds Group 17 Elements Usually form 1 Bond, can form up to 7 Bonds F Cl Cl S Cl TWO electron pairs So TWO BONDS ONE electron pair So ONE BOND
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F Cl F C F Cl N Cl F Covalent Bonds Group 15 Elements
Usually form 3 Bonds, can form up to 5 Bonds Group 14 Elements Usually form 4 Bonds F THREE electron pairs So THREE BONDS Cl F C F Cl N Cl F FOUR electron pairs So FOUR BONDS
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Writing Covalent Compounds
Made of two anions (2 nonmetals or 1 nonmetal & 1 polyatomic ion) Identify the less electronegative element 1st (trend = less EN is the one farthest left & farthest down on Periodic Table) The 1st nonmetal is just given the name as found on the Periodic Table (just like ionic) The 2nd nonmetal ending is changed to –ide (just like ionic…don’t change polyatomics) Difference = numerical prefixes are used to express how many of each nonmetal are present
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Writing Covalent Compounds (cont.)
You never use “criss-cross” method The only time you do not use a prefix is when there is only one of the first nonmetal. Number Prefix 1 Mono 2 Di 3 Tri 4 Tetra 5 Penta 6 Hexa 7 Hepta 8 Octa 9 Nona 10 Deca
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Covalent Compound Practice
Sulfur Dioxide Dinitrogen Monoxide Nitrogen Dioxide Carbon Tetrachloride Dichlorine Heptaoxide Phosphorus Trichloride Sulfur Hexaflouride Trisilicon Tetranitride Nitrogen Pentabromate Water - can use common name SO2 N2O NO2 CCl4 Cl2O7 PCl3 SF6 Si3N4 N(BrO3)5 H2O
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Covalent Compound Practice
Phosphorus Trioxide Dinitrogen Pentacarbide Tellurium Noniodide Carbon Monoxide Selenium Heptaflouride Tetraphosphorous Decoxide Arsenic Hexabromide Silicon Dichloride PO3 N2C5 TeI9 CO SeF7 P4O10 AsBr6 SiCl2
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Ch. 7/8 Notes Day 6
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Objectives SWBAT explain the how transition metals have different properties than Alkali and Alkali Earth Metals SWBAT to explain ionic bonding SWBAT identify charge of transition metals from Roman Numerals
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Naming Acids
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Transition Metals (Groups 3-12)
Become Cations (+ charge) Transition metals are very large Have lots of extra, empty orbitals. Metallic Bond – a bond between transition metals. Electrons are “given off” into a “sea” of electrons that surrounds the metal cations. electron metal cation
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