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Chemical Kinetics – collision theory
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Main Idea Collision theory relates the rates of chemical reaction to collisions between reacting particles. It is the key to understanding why some reactions are faster than others.
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The reaction rate of a chemical reaction is stated as the change in concentration of a reactant or product per unit of time.
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Reaction rates are determined experimentally.
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Collision theory states that atoms, ions, and molecules must collide in order to react. They also must collide with the correct orientation!
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An activated complex is a temporary, unstable arrangement of atoms in which old bonds are breaking and new bonds are forming.
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The minimum amount of energy that reacting particles must have to form the activated complex and lead to a reaction is called the activation energy. High activation energy means that few collisions have the required energy and the reaction rate is slow.
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