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AEROGEL
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HISTORICAL ORIGINS Aerogel was invented some time between 1930 by Dr Samuel Stephen Kistler But actual commercial production was not done till late 1990s .
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WHAT IS AEROGEL …? Aerogels are a diverse class of porous, solid materials which exhibit an uncanny array of extreme materials properties Silica Aerogel Organic and Carbon Aerogels Metal Oxide Aerogels Metal Aerogel
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SPECIAL PROPERTIES OF AEROGEL
extraordinarily strong in compression highest compressive strength to weight ratio of any known material Very high thermal insulation
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RECORDS HELD BY AEROGEL
Lowest density solid ( g /cm3) Lowest optical index of refraction (1.002) Lowest thermal conductivity (0.016W /mK) Lowest speed of sound through a material (70 m/s) Lowest dielectric constant from 3-40 GHz (1.008)
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MANUFACTURING OF AEROGEL
Preparation of a hydrogel (gels with water as a solvent) in reaction of sodium silicate with hydrochloric acid. Removal of sodium and chlorine ions. This step involves a long and tedious soaking of the gel. Converts the hydrogel into alcogel by replacing water with ethyl alcohol in a lengthy process of solvent replacement. Drying at above critical conditions for ethyl alcohol. The balanced chemical equation for the formation of a silica gel from TEOS is: Si(OCH2CH3)4 (liq.) + 2H2O (liq.) = SiO2 (solid) + 4HOCH2CH3 (liq.)
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SUPERCRITICAL DRYING
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Surface Tension and Capillary Stress Shrinkage
The Critical Point Surface Tension and Capillary Stress Shrinkage Properties of Supercritical Fluids CH3OH Methanol C atm CO2 Carbon dioxide C atm
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High-Temperature Supercritical Drying
Most organic solvents have relatively high critical temperatures of °C with critical pressures of atm, and are dangerously flammable and potentially explosive at these conditions.
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Low-Temperature Supercritical Drying from Carbon Dioxide (the Hunt Process)
Instead of using flammable, explosive solvents, a safer, non-flammable solvent can be used instead–carbon dioxide. In this process, the organic solvent in a gel is replaced with liquid carbon dioxide by soaking. The liquid carbon dioxide can supercritically extracted at a much lower temperature (31.1°C) than an organic solvent and without the risk of combustion.
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APPLICATIONS SPACE APPLICATIONS ELECTRICAL AND ELECTRONIC APPLICATIONS
ACOUSTICAL AND MECHANICAL APPLICATIONS OPTICAL PROPERTY APPLICATIONS OPTICAL PROPERTY APPLICATIONS THERMAL APPLICATIONS ( Superinsulator)
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NASA STARDUST COLLECTOR
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THERMAL INSULATION Conduction Convection Radiation
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HIGH STRENGTH TO WEIGHT RATIO
Low Density High Compressive Strength
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OPTICAL PROPERTIES
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Conclusion Aerogel will probably be a common household name in the next decade although it is not yet ready for commercial use. Eco friendly building design ( replace glass pane)
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