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Stable Isotopes in Quaternary Studies
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Applications of stable isotopes
Ice core and past climates Marine sediments, foraminifera and the SPECMAP global ice record Speleothem and paleotemperatures
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H2O Oxygen 16O
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8 protons 8 neutrons + 16O
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8 protons 10 neutrons + 18O
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18O 1 = 16O 2000
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Environmental Isotopes
The Stable Environmental Isotopes Isotope Ratio % natural Reference abundance 2H 2H/1H VSMOW 3He 3He/4He Atmospheric He 13C 13C/12C VPDB 15N 15N/14N AIR N2 18O 18O/16O VSMOW, VPDB 34S 34S/32S CDT 37Cl 37Cl/35Cl SMOC
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Delta - permil: d - ‰ ‰ VSMOW
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Isotope fractionation, a
‰ VSMOW
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Rainout and Rayleigh Distillation
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Rainout and Rayleigh Distillation
heavy isotopes
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Rainout and Rayleigh Distillation
light isotopes heavy isotopes
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d18O in North American Precipitation
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The d18O – T Correlation in Precipitation
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Vostok – a 500 ka Temperature record In an ice core
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The d18O – T Correlation in Precipitation
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T = 1.1 d18O
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Paleo Effect for d18O in precipitation
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Marine sediment cores
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Foraminifera: unicellular marine animals with shells constructed of CaCO3 d18Owater → d18OCaCO3 Proxy record of seawater 18O
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SPECMAP marine sediment record more ice less ice
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Interglacial
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Ice Age -36‰ -20‰
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