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Superbisor: Yong Huang
Exploration of Earth-Abundant Transition Metals (Fe, Co, Ni) as Catalysts in Unreactive Chemical Bond Activations Bo Su, Zhi-Chao Cao, and Zhang-Jie Shi Reporter: Li Li Superbisor: Yong Huang Acc. Chem. Res. 2015, 48, 886
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Concept
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Inert chemical bond activation logic
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Table Fe catalysis Co catalysis Ni catalysis
Fe-catalyzed C-O activation Co catalysis Co-catalyzed C-O activation Ni catalysis Ni-catalyzed eheric C-O activation Ni-catalyzed esteric C-O activation Ni-catalyzed C-O activation of aryl/alkenyl carbamates. Ni-Catalyzed C-O bond activation of phenolates Ni-Catalyzed C-O activation of benzylic alcohols
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Fe catalysis Fe-catalyzed C-O activation
J. Am. Chem. Soc. 2009,131,
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Fe catalysis Fe-catalyzed C-O activation
Chem. Commun. 2013, 49,
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Fe catalysis
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Co catalysis C-O activation J. Chem. Soc. D ,1970, 847
Eur. J.Org. Chem. 2005, 2005, 989 J. Am. Chem. Soc. 2012, 134,14638
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Ni catalysis C-O activation Chem. Commun. 2008, 1437
J. Am. Chem. Soc. 2008, 130, 3268
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Ni catalysis Rational Design of Selective C-O Activation of Carboxylate Chem. Lett. 1976, 1091
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Ni catalysis Selective C−O Activation of Aryl Carboxylates
J. Am. Chem. Soc. 2008, 130, 14468 Chem.Eur. J. 2010, 16, 5844 Angew. Chem., Int. Ed. 2008, 47, 10124
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Ni catalysis Tentative Mechanism of the Ni-Catalyzed Selective C-O Activation of Aryl Carboxylates
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Ni catalysis sp3 C-O Activation of α-Pivaloxyl Ketones
Chem. Commun. 2011, 47, 7224
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Ni catalysis Proposed Mechanism of the Ni-Catalyzed sp3 C-O Activation of α-Pivaloxyl Ketones
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Ni catalysis Selective sp3 C-O Activation of Aryl/Alkenyl Carbamates
Org. Lett. 2010, 12, 884
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Ni catalysis C-O Activation of Magnesium Naphtholates
Angew. Chem. Int.Ed. 2010, 49, 4566
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Ni catalysis Rational Design of the New Mutual Activation Concept
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Ni catalysis C-O Activation of Sodium Naphtholates
Angew.Chem. Int. Ed. 2011, 50, 7097
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Ni catalysis Possible Role of Et3B in the Mutual Activation.
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Ni catalysis sp3 C-O Bond Activation of Benzylic Alcohols
J. Am. Chem. Soc. 2012, 134,14638
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Summary Fe-, Co-, and Ni-catalyzed C-O acivation
Unveiling the relationship between their structures and their reactivity are highly needed Earth abundant transition-metal catalysis VS late transition-metal Aliphatic C-H transformations Designing new ligand for different condition
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A H K N T S
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