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History of Chemistry
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The Greeks 4 elements: - Fire: Hot & Dry - Earth: Dry & Cold
- Water: Cold & Wet - Air: Wet & Hot
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The Alchemists “Fake Scientists” Tried to turn cheap metals into gold
Discovered elements such as mercury and sulfur “The Chymist”
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“The First Chemist” Robert Boyle (1627-1691)
Science should be firmly grounded in experiments. An element is something that cannot be broken down into simpler substances. There are probably many elements.
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II. Elements
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A. Abundant Pure Elements in the Atmosphere
Nitrogen Oxygen Argon
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B. Abundant Elements (By Mass)
Human Body Earth’s Atmosphere Earth’s Oceans Earth’s Crust O (65) C (18) H (10) N (3) Ca (1.5) P (1.2) Others N (78.1) O (20.9) Ar (0.96) C H O (85.8) H (10.8) Cl (1.9) Na (1.1) Others (0.4) Sorry, oil. Lots and lots of oil. O (46.6) Si (27.7) Al (8.1) Fe (5) Ca (3.6) Na (2.8)
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C. Trace Elements Copper - production of red blood cells
Elements that your body needs, but only in small amounts. Examples: Copper - production of red blood cells Iodine - functioning of thyroid gland Chromium - metabolism of sugars
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III. Laws of Matter
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A. Law of Conservation of Mass
Mass can neither be created nor destroyed
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B. Law of Definite Proportion (constant composition)
A given compound always contains exactly the same proportion of elements by mass NaCl: 39.3% Na; 60.7% Cl H2O: 11.1% H; 88.9% O
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C. Law of Multiple Proportions
When 2 elements form a series of compounds, the ratios of the masses of the second element that combine with 1 gram of the first element can always be reduced to whole numbers. Example: H2O * H2O2 1 gram H, 8 grams O 1 gram H, 16 grams O
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The Atom John Dalton (1766-1844)
Dalton’s Atomic Theory Elements are made of tiny particles called atoms. All atoms of a given element are identical. The atoms of a given element are different from those of any other element. Atoms of one element can combine with atoms of other elements to form compounds. A given compound always has the same relative numbers and types of atoms.
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The Atom John Dalton (1766-1844)
Dalton’s Atomic Theory 5. Atoms are indivisible in chemical processes. That is, atoms are not created or destroyed in chemical reactions. A chemical reaction simply changes the way atoms are grouped together.
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The Atom J.J. Thomson ( ) Discovered electrons using the cathode ray tube experiment With Lord Kelvin, he believed that the negative electrons were stuck in a positive sphere (Plum pudding model)
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Cathode Ray Tube
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The Atom Robert Millikan (1909)
Calculated the charge (-1.6 x Coulombs) and mass of an electron using the oil drop experiment
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The Atom Ernest Rutherford (1871-1937)
Discovered the positively charged nucleus using the gold foil experiment. (The atom was mostly empty space, with a dense, positive center.)
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The Atom Gold Foil Experiment
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The Atom Niels Bohr (1913) Believed that electrons moved around the nucleus in rings or shells like planets around the sun (Solar System Model)
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The Atom James Chadwick (1932)
The Atom James Chadwick (1932) Discovered the neutron
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The Atom Quantum Mechanical Model
The Atom Quantum Mechanical Model Electrons exist in orbitals around the nucleus.
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Sources www.chemheritage.org www.aip.org/history
“The Chymist” by David Teniers
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