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Lewis-Acid Base Chemistry and Complexation Equilibria

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Presentation on theme: "Lewis-Acid Base Chemistry and Complexation Equilibria"— Presentation transcript:

1 Lewis-Acid Base Chemistry and Complexation Equilibria
Section 18.3

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4 Aqueous Metal Ions

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6 Also: CO2 is an acid

7 Complexation Reactions and Equilibria

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9 Complex Ion Equilibria
In the presence of excess OH-, the Zn2+(aq) ion forms a hydroxide complex ion. Calculate the concentration of free Zn2+ ion when mol Zn(NO3)2(s) is added to 1.00 L of solution in which [OH-] is held constant (buffered at pH 12.00). Kf(Zn(OH)42- = 4.6 x 1017.

10 Complex Ion Equilibria
In the presence of excess OH-, the Zn2+(aq) ion forms a hydroxide complex ion. Calculate the concentration of free Zn2+ ion when mol Zn(NO3)2(s) is added to 1.00 L of solution in which [OH-] is held constant (buffered at pH 12.00). Kf(Zn(OH)42- = 4.6 x 1017.

11 Solubility of Hydroxide Salts and pH
Calculate the solubility of Fe(OH)2 in solutions below, Ksp = 7.9 x 10-15 pH = 6 pH = 7 pH = 8 pH = 9 pH = 10


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