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Liquid-Liquid Phase Equilibrium
Experiment will be performed in hood
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Purpose To study the miscibility of a binary liquid system as a function of temperature and composition. To determine the distribution coefficient of a binary liquid system. To construct a phase diagram. To determine the critical temperature and mole fraction for the binary system.
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Distribution Coefficient
When methanol and cyclohexane are mixed, there is partial miscibility and two liquid phases are observed. Each phase contains both components. The distribution coefficient is a quantitative measure of how methanol distributes itself quantitatively in each phase. Similarly for cyclohexane.
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Critical T and x Miscibility changes with T and x, mole fraction.
When T is changed for a binary system of constant composition, we can observe the transition from 1-phase to 2-phases and record the transition T. When this T is plotted vs x, the curve may have a maximum or minimum. This is called the critical point.
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Experimental Procedure
Construct a T vs x phase diagram and find the critical point for the methanol-cyclohexane system. Determine the distribution coefficient of the methanol-cyclohexane system.
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