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Ch 7 The Mole and Chemical Composition
What are some things that are sold by weight instead of by number? Which would need a larger package, a kilogram of pencils of a kilogram of drinking straws? If you counted one person per second, how many hours would it take to count the 6 billion people in the world?
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Mole Unit to measure amount of substance whose particles are e same as the number of atoms in exactly 12 g of carbon-12 Avogadro’s number x 1023 Counting unit for large number of particles too small too see
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Molar mass Mass in grams of one mole of a compound or element
Relate moles to mass
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Moles of an element Use moles to count by weight.
? Moles of carbon are in 26g ?= 26 g C x 1mol C = 26 molC =2.2 12.0g C mol 2.2molC x 6.02x1023atoms=1.3x1023 1molC C atoms
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Compounds ? Molecules CO2 in 0.75moles
?=0.75mol CO2x 6.02x1023molecule 1mol CO2 = 4.5x1023molecules CO2
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Relative Atomic Mass Isotopes have different masses
Isotopes have different numbers of neutrons Periodic table – mass is average of all naturally occurring isotopes
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Chemical Formulas and Moles
Formulas- what elements & how many of each Covalent compounds – how many of each element Ionic compounds – simplest ratio of cations to anions Polyatomic ions – simplest ratio of cations to anions
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Molar Mass of a compound
molar mass of elements multiplied by subscript C12H22O11 C = 12.0g x 12 = 144.0g H = 1.0g x 22 = g O = 16.0g x 11 = 176.0g total = g
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Formulas and Percentage Composition
Analyze compounds to find percentage composition Percent by mass of each element in a compound Empirical formula- simplest ratio among the atoms found in a compound C H3 = C2 H6 empirical molecular
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Step one
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Step 2
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Step 3
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Summary
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Percentage Composition
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Find mass of one element
Calculate the mass of zinc in a g sample of zinc nitrate, Zn(NO3)2. Items Data Mass of zinc nitrate 30.00 g Formula of zinc nitrate Zn(NO3)2 Molar mass of zinc nitrate g/mol Mass of zinc in the sample ? g
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Find % of Zn
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Determining Empirical Formulas
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Empirical Formulas Determine the empirical formula for an unknown compound composed of 36.5% sodium, 38.1% oxygen, and 25.4% sulfur by mass.
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Steps 1-4
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Compute
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Mole ratios From the calculations, the simplest mole ratio is 2 mol Na :3 mol O: 1 mol S. The simplest formula is therefore Na2O3S. Seeing the ratio 3 mol O : 1 mol S,
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Molecular Formula A compound is analyzed and found to have the empirical formula CH2O. The molar mass of the compound is found to be 153 g/mol. What is the compound’s molecular formula?
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Plan
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Compute
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Comparing Formulas
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