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Solutions (Don’t write what is in parenthesis)
Chapters 12 and 13
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Universal Solvent – Water
Can dissolve almost every solute Polar molecule – one end is positive and one is negative. Shape is bent (begin with water bubbles) (Draw – like Mickey Mouse – cup of water)
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Hydrogen bonding – attraction of water molecules to each other
Hydrogen bonding – attraction of water molecules to each other. Positive end is attracted to negative end. (Scientists popping water balloons in weightlessness (microgravity) – YouTube) (Drawing)
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Capillary action – The ability of water molecules to climb upward on a porous surface.
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High specific heat capacity – water requires a lot of energy to raise the temperature.
(balloon Demo)
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Surface tension – Attraction of water molecules at the surface.
(Jar Demo)
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Solution - Homogeneous mixture = same composition and properties throughout.
Solvent = does the dissolving - most abundant Solute = substance being dissolved
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Examples Salt water 14 karat gold Air Solute = Solvent =
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(Why does water and oil not mix?
“Like dissolves like” A polar molecule can mix with other polar molecules. Soluble – capable of being dissolved Miscible – will mix Immiscible – will not mix (Why does water and oil not mix? Soaps Vitamins) (Magic sand)
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Factors Affecting the Rate of Dissolving
Increased surface area - cube vs. granules Temperature - different for gases Agitation
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(Solubility) How much solute will dissolve in a certain amount of solvent (Depends on the nature of the solvent, solute, and temperature)
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Saturated Solution = contains maximum amount of dissolved solute
Unsaturated = contains less solute than a saturated solution Supersaturated = solution that contains more dissolved solute than saturated – added solute results in crystallization Video
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(When does the solution become saturated?)
(Look at the solubility of the substance = Amount of substance needed to make a saturated solution at a specific temperature)
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Solubility Curve
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Electrolyte = conducts electricity due to mobile charges in solution
Nonelectrolytes = do not conduct electricity - no ions formed.
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Separation processes Dissociation –
- Ionic compound – polar solvent splits existing ions apart. - Results in a strong electrolyte Ionization – - Covalent compound – polar solvent splits molecule apart, creating ions. - Results in a weak electrolyte
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Concentration = amount of solute in a given amount of solvent
Molarity (M) = measurement of concentration M = mol of solute L of solution
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Molarity Examples You have 0.8 L of a 0.5 M HCl solution. How many moles of HCl does this solution have? (answer 0.4 mol HCl) What volume of 3.00 M NaCl is needed for a reaction that requires g of NaCl? (answer L) 3.5 L of solution contains 90.0 g of NaCl. What is the solution’ s molarity? (0.441 M) How many grams of solute are needed to make 2.50 L of a M solution of Ba(NO3)2? (1140 g)
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Examples: EXAMPLE: 3.5 L of solution contains 90.0 g of NaCl. What is the solution’ s molarity?
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You have 0. 8 L of a 0. 5 M HCl solution
You have 0.8 L of a 0.5 M HCl solution. How many moles of HCl does this solution have?
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Molality Examples What is the molality of a solution composed of 255 g of acetone, (CH3)2CO, dissolved in 200. g of water? (22 m) How many grams of methanol, CH3OH, are required to prepare a solution in g of water? (3.12 g) What is the molality of a solution containing 18.2 g HCl and 250. g of water? (1.99 m)
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Taking a concentrated solution and adding water to make it dilute.
Dilutions Taking a concentrated solution and adding water to make it dilute. M1 V1 = M2 V2
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Example How many mL of a 0.2 M K2Cr2O7 solution is needed to make 100 mL of 0.04 M K2Cr2O7 solution?
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