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Periodic Trends Main Concept: - Many properties of atoms exhibit periodic trends that are reflective of the periodicity of electronic structure.
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Influences on Periodic Trends
1. 2. 3. Trends Ionization Energy Atomic/Ionic Radii Electronegativity Ionic Charges How does each trend change across the periodic table? Why? Periodicity and its Implications
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Periodic Trends - structure of the periodic table is based on electron configuration patterns and presence of shells (and subshells) - electron configuration can be deduced from element’s position in periodic table (with some exceptions)
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Periodic Trends - For many atomic properties, periodic trends below (and relative values for different atoms and ions) can be understood and explained using Coulomb’s law*, the shell model*, and the concept of shielding/effective nuclear charge*. First ionization energy Atomic and ionic radii Electronegativity Typical ionic charges - *Note: This is what you need to draw upon to explain anything on the periodic table
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- First ionization energy: how much energy is needed to pull off the first valence electron
- Atomic radii: the size of an atom - Ionic radii: the size of an atom once it has given up or gained electrons - Electronegativity: the ability of an atom to pull electrons towards itself while bonded - Typical Ionic Charges: metals give up electrons making them slightly positive; nonmetals will take electrons making them slightly negative
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Question: Why would anions be larger than their parent atom?
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- Periodicity = useful tool when designing new molecules or materials
- replacing an element of one group with another of the same group may lead to a new substance with similar properties. ex: if SiO2 can be ceramic, SnO2 may be also
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Question: Why would elements in the same group have similar properties? Why might those same elements have slightly different properties? Based on electron configurations, why would groups 1 and 2 be most likely to give up electrons while group 16 and 17 be most likely to take electrons while group 18 would do neither?
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