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Organic Compounds
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Organic Molecules Generally, molecules that contain carbon are organic
Some exceptions are carbonates (CO32-), cyanides (CN-), simple oxides of carbon (CO), as well as diamond and graphite Diamond and graphite are allotropes of carbon—that is, they are just carbon, but in very different structural forms.
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Organic Molecules / Hydrocarbons
Hydrocarbons are organic molecules that contain only carbon and hydrogen. Methane, CH4, is the simplest hydrocarbon.
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Organic Molecules Other organic molecules may contain many other elements including halogens, metals, sulfur, oxygen, phosphorus, or nitrogen. I C8H10N402
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Organic Compounds Organic compounds make up the whole or part of innumerable products—some natural and some synthetic. Synthetic examples include: Plastics Explosives Paints Petrochemicals – hydrocarbons derived from petroleum that are used to make synthetic compounds such as plastic
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4 types of Organic Molecule: Carbohydrates: sugars, starches (C,H,O)
Natural Examples: ?? Remember in Biology!! 4 types of Organic Molecule: Carbohydrates: sugars, starches (C,H,O) Proteins: amino acids (C,H,O,P) Nucleic Acids: DNA & RNA (C,H,O,N) Lipids: Fats/Oils/Wax, Cell Membranes, Hormones.. (C,H,O,P,S) Pharmaceuticals aspirin, vitamins, insulin
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Structure Organic molecules are constructed as carbon atoms form 4 stable, covalent bonds.
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Structure These carbon structures can have single, double, or triple bonds. They can be straight chains or chains with branches. They can also form rings.
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Alkanes: Saturated Hydrocarbons
Remember: Hydrocarbons are molecules composed of C & H. Each carbon atom forms 4 chemical bonds A saturated hydrocarbon is one where all C - C bonds are “single” bonds & the molecule contains the maximum number of H-atoms. Saturated hydrocarbons are called ALKANES
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Alkane Naming System Butane! Octane!
Alkanes are named using a prefix + “ane.” The prefix is determined by the number of carbons. An alkane with 1 carbon is called methane; 2 carbons is called ethane, etc. Meth – 1 Pent – 5 Eth – 2 Hex – 6 Prop – 3 Hept – 7 But – 4 Oct – 8 What would this alkane be called? Butane! What would this alkane be called? C8H18 Octane!
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Drawing Alkane Structures
Using the prefix, determine how many carbons are in the chain. Connect each carbon with a single bond. Add hydrogens so that each carbon is saturated. Remember that carbon forms 4 bonds. For example, draw propane.
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Alkenes and Alkynes Alkenes contain a double bond between adjacent carbon atoms. Alkynes contain a triple bond. These hydrocarbons are called unsaturated because all of the bonds are NOT single bonds. Copyright © by Pearson Education, Inc. Publishing as Benjamin Cummings
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Functional Groups Carbon atoms bound to each other form a backbone to which other atoms or groups of atoms are attached. These groups of atoms are called functional groups.
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Dashes and Wedges Used to show 3-D
Straight lines are in the same plane Wedges come out of the plane Dashes go back into the plane
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In the chart below, indicate under the name whether the compounds are hydrocarbons and if so, whether they are saturated or unsaturated. Circle and label any functional groups. The C-H bond is nonpolar. The presence of lone pairs produces a polarity. Polar substances will dissolve in a polar solvent such as water. Nonpolar substances will only dissolve in nonpolar solvents.
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Structure CH3CH2OH CH4 CH2O C2H6 C6H6 C2H4 CH3COOH C2H2 Methane
Ethanol Ethane Formaldehyde Benzene Ethene Acetylene Acetic Acid
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Structure / Polymers When organic molecules form long chains with repeating structural units, they are called polymers. These chains are flexible—the bonds in the backbone can swivel like paperclips hooked together.
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Structure / Polymers Insulin (a protein)
Polymers can be natural or synthetic Natural: Proteins, cellulose, RNA, amino acids and DNA Synthetic: Plastic, nylon, and Kevlar
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Polymers Rubber
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Properties of Organic Compounds
Covalent bonds Low melting and boiling points Often liquids or gases at room temperature and pressure
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Chemistry Joke Q: What did the bartender say when oxygen, hydrogen, sulfur, sodium, and phosphorus walked in? A: OH SNaP!!!
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