1. Contrasting complexes of hydrogen and hydrogen fluoride by high resolution spectroscopy

3. The structure of the complex of hydrogen and carbonyl
sulfide. For oH2-OCS the complex is planar with the
rotation of the hydrogen species quenched by the
weak intermolecular interaction. For pH2-OCS the
hydrogen is spherically distributed. The similarity of the
frequencies of the rotational transitions of oH2-OCS
and pH2-OCS is striking and completely surprised us.

7. BIBLIOGRAPHY OF ROTATIONAL SPECTRA OF WEAKLY BOUND COMPLEXES
Stewart Novick
Department of Chemistry
Wesleyan University
Middletown, Connecticut
wesleyan.edu/chem/faculty/novick/vdw.html

10. Ar F H ∑1
JHF = 1 H Ar F ∏1
JHF = 1 Ar F H ∑o
JHF = 0

14. EArHF - EHF, j asymptotic
cm-1 ^H
Ar | F ∏1
J=1 ∑1
Ar—>FH ∑0
Ar<—HF

16. ∑0 Ar<—HF ∑ 1 B Ar<—FH RAr-F~ √1/B ∏1 R≈3.52±.03 H Ar F v rout Å
.104 ∑0
Ar<—HF
.103 ∑ B
Ar<—FH
.102
RAr-F~ √1/B ∏1
cm-1
R≈3.52±.03
.101 H
Ar F
.100 v
rout Å
rin