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Lipids (fats) Main Function: long-term energy storage Special Feature: contain more energy per gram than any other biological molecule Groupings: Mostly C and H atoms(hydrocarbons) Types: 1. Triglycerides Steroids 2. Phospholipids Animal fat room temp) Plant oils room temp) 1 2 3 4 Which are made of which contain Carbohydrates Lipids Nucleic acids (e.g., DNA/RNA) Proteins Simple sugars (e.g., glucose) Glycerol & 3 Fatty Acids Nucleotides Amino Acids Carbon, hydrogen, oxygen Carbon, hydrogen oxygen, nitrogen, phosphorus hydrogen, oxygen, nitrogen, main function main function main function main function CATALYSIS & STRUCTURE /SUPPORT ENCODING HEREDITARY INFORMATION ENERGY STORAGE ENERGY STORAGE short-term long-term
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Structure of Lipids (fats)
1 2 3 Glycerol Fatty acids
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1. Triglycerides FA Glycerol FA = TG (Triglyceride) FA Structure
Triglycerides are composed of 1 glycerol + 3 fatty acids (16-18 Carbons long) Formation and Breakdown Triglycerides are formed through a condensation/dehydration reaction between the glycerol and each of the fatty acids. Triglycerides are broken down into 1 glycerol and 3 fatty acids through hydrolysis 2 Types of Fatty Acids Saturated Unsaturated
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Making and Breaking Lipids (fats)
Fats and oils are called triglycerides because of their structure 1 Ester linkage + 3 H2O Condensation Synthesis Hydrolysis main function ENERGY STORAGE short-term
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Types of Fatty Acids Saturated Unsaturated Poly - unsaturated
# of Double Bonds between Carbons At least one double bond between carbon atoms None (contains maximum # of H atoms) Several double bonds
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Types of Fatty Acids: Saturated
Saturated Fats Solid at room temperature Contain only single C-C bonds (resulting in straight chains) During digestion these are converted into “bad cholesterol” which can clog arteries Ex. animal fats, butter
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Types of Fatty Acids Fewer hydrogens – “unsaturated”
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CH2-CH =CH Types of Fatty Acids BEND DUE TO DOUBLE BOND
How do you think this bend affects density???
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Types of Fatty Acids: Unsaturated
Unsaturated Fats Liquid at room temperature Contain double C-C bonds (resulting in kinks in their chains) Unsaturated fats with more than one double bond are called polyunsaturated fats Ex. vegetable oils
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Trans Fat Types of Fatty Acids
Taking a perfectly good fat and making it bad! Unsaturated fat (contains double bonded carbons) that has the properties of a saturated fat Often solid at room temperature Bad for you! Also causes an increase in “bad cholesterol”
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How Trans Fats Became out Enemy…
Fill out the question sheet while you watch this short YouTube clip
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Phospholipids Fat derivatives in which one fatty acid has been replaced by a phosphate group and one of several nitrogen-containing molecules. an important part of the cell membrane (phospholipid bilayer)
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Phospholipids Structure:
Composed of glycerol, 2 fatty acids, and a phosphate-containing functional group Phosphate head is hydrophillic (water-loving) and the fatty acid tails are hydrophobic (water-hating) Why do you think the fatty acids are hydrophobic? Why is the phosphate portion hydrophillic?
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The phospholipid can also be represented as:
Phospholipids The phospholipid can also be represented as: Polar Head – hydrophilic (water-loving) Non-Polar Tails (fatty acids) – hydrophobic (water-hating)
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Steroids Testosterone Cholesterol
Very different structure to other lipids Made of 4 fused carbon rings Include hormones such as testosterone, estrogen, etc.
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